Technology Process of 2-allyl-1-benzyloxy-9,10-anthraquinone
There total 1 articles about 2-allyl-1-benzyloxy-9,10-anthraquinone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate; potassium iodide;
In
N,N-dimethyl-formamide;
at 65 ℃;
for 1h;
Inert atmosphere;
DOI:10.1021/ja405400k
- Guidance literature:
-
2-allyl-1-benzyloxy-9,10-anthraquinone;
With
ozone;
In
dichloromethane;
at -78 ℃;
for 0.25h;
Inert atmosphere;
With
dimethylsulfide;
In
dichloromethane;
at 20 ℃;
for 10h;
Inert atmosphere;
DOI:10.1021/ja405400k
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: ozone / dichloromethane / 0.25 h / -78 °C / Inert atmosphere
1.2: 10 h / 20 °C / Inert atmosphere
2.1: 2-methyl-but-2-ene; sodium dihydrogen phosphate monohydrate; sodium chlorite / tert-butyl alcohol; tetrahydrofuran; water / 0 - 20 °C / Inert atmosphere
3.1: benzotriazol-1-ol; N-ethyl-N,N-diisopropylamine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0 - 20 °C / Inert atmosphere
With
sodium chlorite; sodium dihydrogen phosphate monohydrate; 2-methyl-but-2-ene; benzotriazol-1-ol; ozone; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
DOI:10.1021/ja405400k
