(±)-N-benzylidenebezenesulfinamide

Base Information

• Chemical Name: (±)-N-benzylidenebezenesulfinamide
• CAS No.: 52778-10-6
• Molecular Formula: C₁₃H₁₁NOS
• Molecular Weight: 229.302
• Mol file: 52778-10-6.mol

Synonyms:(±)-N-benzylidenebezenesulfinamide

Chemical Property of (±)-N-benzylidenebezenesulfinamide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (±)-N-benzylidenebezenesulfinamide

There total 9 articles about (±)-N-benzylidenebezenesulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

N-benzylidene-S-phenylthiohydroxylamine (52777-99-8) → (±)-N-benzylidenebezenesulfinamide (52778-10-6)

Guidance literature:

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In chloroform; water;

Reference yield: 93.0%

N-chloro-S-benzyl-S-phenylsulfoximide (85313-82-2) → (±)-N-benzylidenebezenesulfinamide (52778-10-6)

Guidance literature:

With 1,5-Diazabicyclo[5.4.0]undec-5-ene; In dichloromethane; for 0.0833333h; Ambient temperature;

Reference yield: 91.0%

benzenesulfinamide (16066-31-2,33903-53-6) + benzyl alcohol (100-51-6,185532-71-2) → (±)-N-benzylidenebezenesulfinamide (52778-10-6)

Guidance literature:

With copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium carbonate; L-proline; In toluene; at 60 ℃; for 24h; Molecular sieve; Green chemistry;

DOI:10.1039/c6ra26490e

upstream raw materials:

N-benzylidene-S-phenylthiohydroxylamine

N-chloro-S-benzyl-S-phenylsulfoximide

N-bromo-S-benzyl-S-phenylsulfoximide

α-azidobenzyl phenyl sulfoxide

Downstream raw materials:

methyl (E)-3-phenylsulfinylprop-2-enoate

Trimethylsilyl Benzenesulfenate

benzonitrile

Refernces

• 1、 Zhang, Guofu,Xu, Shengjun,Xie, Xiaoqiang,Ding, Chengrong,Shan, Shang. "Direct synthesis of N-sulfinyl- and N-sulfonylimines via copper/l-proline-catalyzed aerobic oxidative cascade reaction of alcohols with sulfinamides or sulfonamides". . p. 9431 - 9435. Retrieved 2017/02/15.
• 2、 Jarvis, Bruce B.,Nicholas, Paul E.,Midiwo, Jacob O.. "Thermolysis of α-Azido Sulfides, Sulfoxides, and Sulfones: Dependence of Mechanism on Oxidation State of Sulfur". . p. 3878 - 3882. Retrieved 2007/10/02.