52777-99-8 Usage
Classification
Sulfenamide derivative
1-phenyl-N-(phenylsulfanyl)methanimine belongs to the class of compounds known as sulfenamides, which are characterized by the presence of a sulfur atom bonded to a nitrogen atom and an amide group.
Substitution groups
Phenyl group attached to both nitrogen and sulfur atoms
In this compound, both the nitrogen and sulfur atoms have a phenyl group (a ring of six carbon atoms with alternating single and double bonds) attached to them, which influences its chemical properties and reactivity.
Usage
Organic synthesis reagent
1-phenyl-N-(phenylsulfanyl)methanimine is commonly used in organic synthesis as a reagent for the preparation of various organic compounds, making it a valuable building block in the synthesis of pharmaceuticals, agrochemicals, and other organic molecules.
Potential applications
Pharmaceutical and agrochemical development
Physical state
Solid at room temperature
This chemical compound is a solid at room temperature, which affects its handling, storage, and potential use in various applications.
Aromatic odor
Characteristic
1-phenyl-N-(phenylsulfanyl)methanimine has a characteristic aromatic odor, which is typical for compounds containing a benzene ring structure.
Safety precautions
Harmful if ingested, inhaled, or in contact with skin
It is important to handle 1-phenyl-N-(phenylsulfanyl)methanimine with care, as it may be harmful if ingested, inhaled, or comes into contact with the skin. Proper safety measures, such as wearing gloves and a lab coat, should be taken when working with this compound.
Check Digit Verification of cas no
The CAS Registry Mumber 52777-99-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,2,7,7 and 7 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 52777-99:
(7*5)+(6*2)+(5*7)+(4*7)+(3*7)+(2*9)+(1*9)=158
158 % 10 = 8
So 52777-99-8 is a valid CAS Registry Number.
52777-99-8Relevant articles and documents
Copper-catalyzed oxidative N-S bond formation for the synthesis of N-sulfenylimines
Lee, Chan,Wang, Xi,Jang, Hye-Young
supporting information, p. 1130 - 1133 (2015/03/14)
Despite the remarkable success of the copper-catalyzed oxidative coupling reaction, direct cross-coupling of amines and thiols for the synthesis of N-sulfenylimines has not been previously reported. Using commercially available copper catalysts (CuI) and
Thermolysis of α-Azido Sulfides, Sulfoxides, and Sulfones: Dependence of Mechanism on Oxidation State of Sulfur
Jarvis, Bruce B.,Nicholas, Paul E.,Midiwo, Jacob O.
, p. 3878 - 3882 (2007/10/02)
Thermolyses of α-azidobenzyl phenyl sulfide (1), sulfoxide (3), and sulfone (2) proceed at markedly different rates.Sulfone 2 requires the highest temperature (> 150 deg C), whereas sulfide 1 loses nitrogen at 120 deg C with neighboring group participation by the sulfur atom to produce N-benzylidenebenzenesulfenamide 4 in 75percent yield.Sulfoxide 3 readily decomposes at 70 deg C through a radical-pair intermediate, which gives rise to a CIDNP effect in the reaction products.Kinetic data are presented supporting the suggested reaction mechanisms.
