5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

Base Information

Chemical Name:5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol
CAS No.:514204-21-8
Molecular Formula:C₄₆H₃₈N₂O₁₂
Molecular Weight:810.814
Hs Code.:

Synonyms:5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

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Chemical Property of 5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

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Technology Process of 5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

There total 4 articles about 5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 67-56-1
methanol

: 514204-20-7
5,17-bis(3-nitrophenyl)-25,27-bis(hydroxycarbonylmethoxy)calix[4]arene-26,28-diol

: 514204-21-8
5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

Guidance literature:: With sulfuric acid; In chloroform; for 12h; Heating;
DOI:10.1021/jo026522+

Reference yield:

: 248590-47-8,74568-07-3
25,26,27,28-tetrakis(hydroxy)calix[4]arene

: 514204-21-8
5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / dimethylformamide; tetrahydrofuran

2: 99 percent / Br₂ / CHCl₃ / 3 h / 20 °C

3: 78 percent / Na₂CO₃; Pd(PPh₃)4 / toluene; methanol; H₂O / 40 h / 70 °C

4: 99 percent / conc. H₂SO₄ / CHCl₃ / 12 h / Heating

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sulfuric acid; bromine; sodium hydride; sodium carbonate; In tetrahydrofuran; methanol; chloroform; water; N,N-dimethyl-formamide; toluene;
DOI:10.1021/jo026522+

Reference yield:

: 142267-55-8
25,27-bis[(ethoxycarbonyl)methoxy]-26,28-dihydroxycalix[4]arene

: 514204-21-8
5,17-bis(3-nitrophenyl)-25,27-bis(methoxycarbonylmethoxy)calix[4]arene-26,28-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / Br₂ / CHCl₃ / 3 h / 20 °C

2: 78 percent / Na₂CO₃; Pd(PPh₃)4 / toluene; methanol; H₂O / 40 h / 70 °C

3: 99 percent / conc. H₂SO₄ / CHCl₃ / 12 h / Heating

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sulfuric acid; bromine; sodium carbonate; In methanol; chloroform; water; toluene;
DOI:10.1021/jo026522+