ruthenium pentafluoride

Base Information

• Chemical Name: ruthenium pentafluoride
• CAS No.: 14521-18-7
• Molecular Formula: F5Ru
• Molecular Weight: 196.062
• Hs Code.: 2826908090
• Mol file: 14521-18-7.mol

Synonyms:Rutheniumfluoride (Ru2F10); Ruthenium pentafluoride; Ruthenium pentafluoride (RuF5)

Chemical Property of ruthenium pentafluoride

Chemical Property:

• Vapor Pressure: 922mmHg at 25°C
• Melting Point: 86.5°C
• Boiling Point: 19.5°C at 760 mmHg
• PSA: 0.00000
• Density: 3.900
• LogP: -11.98400

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ruthenium pentafluoride

There total 16 articles about ruthenium pentafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

fluorine (7782-41-4) + ruthenium (7440-18-8) → ruthenium(VI) fluoride (13693-08-8) + ruthenium(V) fluoride (14521-18-7)

Guidance literature:

In neat (no solvent); heating 1 g Ru powder in an atmosphere of F2 (300 Torr) in a quartz cylinder cooled with liquid N2; stop heating when react. starts; pptn. of RuF6 in a freezing trap;; removal of RuF5 by vac. distn. at ambient temp.;;

DOI:10.1021/ja01471a039

Reference yield: 35.0%

fluorine (7782-41-4) + ruthenium (7440-18-8) → ruthenium(V) fluoride (14521-18-7)

Guidance literature:

In neat (no solvent); An F2 stream is passed over finely powdered Ru, which has been annealed in a H2 stream; Pt apparatus, at 290 °C, moisture excluded;; redistd. in an F2 stream at 260 °C; sepn. from PtF4 by distn. in an N2 stream at 260 °C;;

Reference yield:

ruthenium(VI) fluoride (13693-08-8) → ruthenium(V) fluoride (14521-18-7) + fluorine (7782-41-4)

Guidance literature:

In neat (no solvent); complete decompn. at 200 °C;;

DOI:10.1021/ja01471a039

upstream raw materials:

fluorine

ruthenium

xenon difluoride

chlorine

Downstream raw materials:

molybdenum trifluoride

ruthenium

NbF₃

niobium tetrafluoride

Refernces

• 1、 Darriet,Lozano. "MAGNETIC PROPERTIES OF RuF5.". . p. 493 - 496. Retrieved 1979.
• 2、 McNamara, Bruce K.,Buck, Edgar C.,Soderquist, Chuck Z.,Smith, Frances N.,Mausolf, Edward J.,Scheele, Randall D.. "Separation of metallic residues from the dissolution of a high-burnup BWR fuel using nitrogen trifluoride". supporting information. p. 1 - 8. Retrieved 2014/05/06.