Butyl 3-(trichlorostannyl)propionate

Base Information

Chemical Name:Butyl 3-(trichlorostannyl)propionate
CAS No.:61470-34-6
Molecular Formula:C7H13Cl3O2Sn
Molecular Weight:354.248
Hs Code.:2931900090
European Community (EC) Number:262-808-1
DSSTox Substance ID:DTXSID4069474
Wikidata:Q81996370
Mol file:61470-34-6.mol

Synonyms:Butyl 3-(trichlorostannyl)propionate;61470-34-6;3-(Trichlorostannyl)propanoic acid, butyl ester;EINECS 262-808-1;Propanoic acid, 3-(trichlorostannyl)-, butyl ester;C7H13Cl3O2Sn;C7-H13-Cl3-O2-Sn;SCHEMBL9777650;DTXSID4069474;beta-n-butoxycarbonylethyl tin trichloride

Suppliers and Price of Butyl 3-(trichlorostannyl)propionate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Butyl 3-(trichlorostannyl)propionate

Chemical Property:

Vapor Pressure:0.000178mmHg at 25°C
Boiling Point:329.4°C at 760 mmHg
Flash Point:153°C
PSA：26.30000
LogP:-8.08260
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:353.900315
Heavy Atom Count:13
Complexity:158

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCOC(=O)CC[Sn](Cl)(Cl)Cl

Technology Process of Butyl 3-(trichlorostannyl)propionate

There total 5 articles about Butyl 3-(trichlorostannyl)propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 141-32-2,9003-49-0
acrylic acid n-butyl ester

: tin(ll) chloride

: 27387-79-7
3-chloro-propionic acid butyl ester

: 61470-34-6
C₇H₁₃Cl₃O₂Sn

Guidance literature:: With hydrogenchloride; In neat (no solvent); under N2 atm. to suspn. anhyd. SnCl2 in butylacrylate added anhyd. HCl during 2 h, temp. maintained at 20°C or below; react. mixt. kept at 150°C/4 mm Hg to remove unreacted butylacrylate and ClCH2CH2COOBu, residue filtered; elem. anal.;
DOI:10.1016/S0020-1693(00)83624-5

Reference yield: 88.4%

: 59586-13-9
methyl 3-(trichlorostannyl)propanoate

: 71-36-3
butan-1-ol

: 61470-34-6
C₇H₁₃Cl₃O₂Sn

Guidance literature:: In butan-1-ol; byproducts: MeOH; reflux for 2 h; soln. was concd. in vac., solid was recrystd. from CH2Cl2-petroleum ether (30-60 °C) (1:1, v/v), elem. anal.;
DOI:10.1080/00945710009351839

Reference yield:

: 7647-01-0,15364-23-5
hydrogenchloride

: 7440-31-5
tin

: 141-32-2,9003-49-0
acrylic acid n-butyl ester

: 61470-34-6
β-n-butoxycarbonylethyltin trichloride

: 61470-33-5
Cl₂Sn(CH₂CH₂COOCH₂CH₂CH₂CH₃)2

Guidance literature:: In diethyl ether; reaction of tin, CH3CH2CH2OCOCH=CH2 and dry HCl in ethyl ether, productmixt extd. by warm CHCl3; purifn. of monoester by fractional recrystn.;
DOI:10.1016/0022-328X(83)85115-8