1-(Diphenylphosphino)-2-(dimethylsilyl)benzene

Base Information

Chemical Name:1-(Diphenylphosphino)-2-(dimethylsilyl)benzene
CAS No.:1435872-01-7
Molecular Formula:C₂₀H₂₁PSi
Molecular Weight:320.446
Hs Code.:
DSSTox Substance ID:DTXSID001254369
Nikkaji Number:J2.207.823B

Synonyms:DTXSID001254369;Phosphine, [2-(dimethylsilyl)phenyl]diphenyl-;1-(Diphenylphosphino)-2-(dimethylsilyl)benzene;1435872-01-7

Suppliers and Price of 1-(Diphenylphosphino)-2-(dimethylsilyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(Diphenylphosphino)-2-(dimethylsilyl)benzene

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:4
Exact Mass:319.10718917
Heavy Atom Count:22
Complexity:300

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)C1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of 1-(Diphenylphosphino)-2-(dimethylsilyl)benzene

There total 3 articles about 1-(Diphenylphosphino)-2-(dimethylsilyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1066-35-9
dimethylmonochlorosilane

: 62336-24-7
(2-bromophenyl)diphenylphosphane

: 1435872-01-7
(2-diphenylphosphinophenyl)dimethylsilane

Guidance literature:: (2-bromophenyl)diphenylphosphane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

dimethylmonochlorosilane; at -78 ℃; for 0.5h;
DOI:10.1039/c3dt32408g

Reference yield:

: 829-85-6
diphenylphosphane

: 1435872-01-7
(2-diphenylphosphinophenyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / toluene / 12 h / 80 °C / Inert atmosphere

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -78 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; triethylamine; In tetrahydrofuran; hexane; toluene;
DOI:10.1039/c3dt32408g

Reference yield:

: 583-55-1
1-Bromo-2-iodobenzene

: 1435872-01-7
(2-diphenylphosphinophenyl)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine / toluene / 12 h / 80 °C / Inert atmosphere

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -78 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; triethylamine; In tetrahydrofuran; hexane; toluene;
DOI:10.1039/c3dt32408g