4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde

Base Information

• Chemical Name: 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde
• CAS No.: 943784-70-1
• Molecular Formula: C₄₃H₂₉N₃OS₂
• Molecular Weight: 667.855
• Mol file: 943784-70-1.mol

Synonyms:4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde

Chemical Property of 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde

There total 2 articles about 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

4-[bis-(4-iodophenyl)amino]benzaldehyde (808758-81-8) + 10H-phenothiazine (92-84-2) → 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde (943784-70-1)

Guidance literature:

With 18-crown-6 ether; potassium carbonate; In 1,2-dichloro-benzene; at 180 ℃; for 48h; Inert atmosphere;

DOI:10.1002/pola.24127

Reference yield:

4-(diphenylamino)benzaldehyde (4181-05-9) → 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde (943784-70-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 75 percent / potassium iodide; potassium iodate; acetic acid / H₂O / 3 h / 80 °C

2: 56 percent / potassium carbonate; copper bronze; 18-crown-6 / 1,2-dichloro-benzene / Heating

With potassium iodate; 18-crown-6 ether; copper; potassium carbonate; acetic acid; potassium iodide; In water; 1,2-dichloro-benzene; 2: Ullmann reaction;

DOI:10.1039/b614235d

Reference yield: 69.0%

4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}benzaldehyde (943784-70-1) + Methyltriphenylphosphonium bromide (1779-49-3) → 4-{bis[4-(10H-phenothiazin-10-yl)phenyl]amino}-1-vinylbenzene

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 0 ℃;

DOI:10.1039/b614235d

upstream raw materials:

4-[bis-(4-iodophenyl)amino]benzaldehyde

10H-phenothiazine

4-(diphenylamino)benzaldehyde