6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

Base Information

Chemical Name:6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose
CAS No.:1621188-31-5
Molecular Formula:C₂₅H₄₂O₅Si₂
Molecular Weight:478.776
Hs Code.:

Synonyms:6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

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Chemical Property of 6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

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Technology Process of 6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

There total 3 articles about 6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 69304-37-6
1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane

: 165524-85-6
6-O-(benzyl)-D-glucal

: 1621188-31-5
6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 5h;
DOI:10.1002/anie.201403543

Reference yield:

: 100-39-0
benzyl bromide

: 1621188-31-5
6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / N,N-dimethyl-formamide; tetrahydrofuran / 6 h / -40 - 0 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 5 h / 0 - 20 °C

With 1H-imidazole; lithium hexamethyldisilazane; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/anie.201403543

Reference yield:

: 13265-84-4
D-glucal

: 1621188-31-5
6-O-benzyl-1,2-dideoxy-3,4-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-D-arabino-1-hexenopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / N,N-dimethyl-formamide; tetrahydrofuran / 6 h / -40 - 0 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 5 h / 0 - 20 °C

With 1H-imidazole; lithium hexamethyldisilazane; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1002/anie.201403543