9-FluorenylMethylthiol

Base Information

Chemical Name:9-FluorenylMethylthiol
CAS No.:957753-00-3
Molecular Formula:C₁₄H₁₂S
Molecular Weight:212.315
Hs Code.:
Mol file:957753-00-3.mol

Synonyms:(9H-fluoren-9-yl)methanethiol

Suppliers and Price of 9-FluorenylMethylthiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
9-Fluorenylmethylthiol 97%
1g
$ 632.00

Sigma-Aldrich
9-Fluorenylmethylthiol 97%
250mg
$ 189.00

American Custom Chemicals Corporation
9-FLUORENYLMETHYLTHIOL 95.00%
1G
$ 1267.17

Total 1 raw suppliers

Chemical Property of 9-FluorenylMethylthiol

Chemical Property:

Melting Point:31-36°C
Boiling Point:368.2±11.0 °C(Predicted)
PKA:8.95±0.25(Predicted)
Density:1.157±0.06 g/cm3(Predicted)

Purity/Quality:

97% ^*data from raw suppliers

9-Fluorenylmethylthiol 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:N
Statements: 50/53
Safety Statements: 60-61

MSDS Files:

Useful:

Uses This novel material is capable of self-assembly onto gold surfaces. The fluorene group is a precursor for the synthesis of luminophore materials that have longer lifespans and more efficient luminescence. The methylene group provides flexibility and a potential point of chirality.

Technology Process of 9-FluorenylMethylthiol

There total 3 articles about 9-FluorenylMethylthiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 9-fluorenylmethyl thioacetate

: 957753-00-3
(9H-fluoren-9-yl)methanethiol

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; toluene; at -78 - 0 ℃; for 0.5h;
DOI:10.1021/ol701583t

Reference yield:

: 24324-17-2
9-Fluorenylmethanol

: 957753-00-3
(9H-fluoren-9-yl)methanethiol

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / chloroform / 0 - 22 °C

2: N,N-dimethyl-formamide / 2 h / 20 - 22 °C

3: diisobutylaluminium hydride / diethyl ether / 1.08 h / -78 - 0 °C / Inert atmosphere

With pyridine; diisobutylaluminium hydride; In diethyl ether; chloroform; N,N-dimethyl-formamide;
DOI:10.1039/c7ob01995e

Reference yield:

: 71532-40-6
(9H-fluoren-9-yl)methyl 4-methylbenzenesulfonaye

: 957753-00-3
(9H-fluoren-9-yl)methanethiol

Guidance literature:: Multi-step reaction with 2 steps

1: N,N-dimethyl-formamide / 2 h / 20 - 22 °C

2: diisobutylaluminium hydride / diethyl ether / 1.08 h / -78 - 0 °C / Inert atmosphere

With diisobutylaluminium hydride; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1039/c7ob01995e