S-benzyl O,O-diethyl phosphorothioite

Base Information

• Chemical Name: S-benzyl O,O-diethyl phosphorothioite
• CAS No.: 114105-41-8
• Molecular Formula: C₁₁H₁₇O₂PS
• Molecular Weight: 244.295
• Mol file: 114105-41-8.mol

Synonyms:S-benzyl O,O-diethyl phosphorothioite

Chemical Property of S-benzyl O,O-diethyl phosphorothioite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of S-benzyl O,O-diethyl phosphorothioite

There total 2 articles about S-benzyl O,O-diethyl phosphorothioite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

diethyl 1-methyl-3-oxobut-1-enyl phosphite (70971-86-7) + phenylmethanethiol (100-53-8) → S-benzyl O,O-diethyl phosphorothioite (114105-41-8) + acetylacetone (123-54-6,81235-32-7)

Guidance literature:

for 96h;

Reference yield:

diethyl phosphorylchloridite (589-57-1) + benzylthiotrimethylsilane (14629-67-5) → S-benzyl O,O-diethyl phosphorothioite (114105-41-8)

Guidance literature:

at 20 ℃; for 24h;

DOI:10.1007/BF00960423

Reference yield:

S-benzyl O,O-diethyl phosphorothioite (114105-41-8) → O,O-diethylbenzylthiophosphonate (73178-33-3)

Guidance literature:

With oxygen; Yield given;

DOI:10.1007/BF00960423

upstream raw materials:

diethyl phosphorylchloridite

benzylthiotrimethylsilane

diethyl 1-methyl-3-oxobut-1-enyl phosphite

phenylmethanethiol

Downstream raw materials:

O,O-diethylbenzylthiophosphonate

Refernces

• 1、 Ustanova, L. N.,Burilov, A. R.,Belyalov, R. U.,Gazizov, T. Kh.,Pudovik, M. A.,Pudovik, A. N.. "SYNTHESIS OF O,O,S-TRIALKYL PHOSPHOROTHIOITES". . p. 1278. Retrieved 2007/10/02.