73178-33-3Relevant academic research and scientific papers
Preparation of benzylphosphonates via a palladium(0)-catalyzed cross-coupling of H-phosphonate diesters with benzyl halides. Synthetic and mechanistic studies
Laven, Gaston,Kalek, Marcin,Jezowska, Martina,Stawinski, Jacek
scheme or table, p. 967 - 975 (2010/08/04)
We have developed a new, efficient method for the synthesis of benzylphosphonate and benzylphosphonothioate diesters via a palladium(0)- catalyzed cross-coupling reaction between benzyl halides and H-phosphonate or H-phosphonothioate diesters, using Pd2(dba)3(CHCl 3) as a palladium source and Xantphos as a supporting ligand. Some mechanistic aspects of these reactions were investigated using 31P NMR spectroscopy.
PHASE-TRANSFER CATALYTIC ALKYLATION OF HYDROTHIOPHOSPHORYL COMPOUNDS. IV. REACTIONS WITH PRIMARY ALKYL HALIDES
Aladzheva, I. M.,Odinets, I. L.,Petrovskii, P. V.,Mastryukova, T. A.,Kabachnik, M. I.
, p. 431 - 437 (2007/10/02)
A convenient general method for the synthesis of compounds containing a thiophosphoryl group was elaborated on the basis of the Michaelis-Becker reaction with the use of the method of phase-transfer catalysis. The influence of the nature of the hydrothiophosphoryl compounds, of the alkylating agents, and of the reaction conditions on the yields of alkylated products was investigated in detail.
INTERACTION OF THIOESTERS OF P(III) WITH OXYGEN
Burilov, A. R.,Drozdova, Ya. A.,Pudovik, M. A.,Pudovik, A. N.
, p. 1885 - 1890 (2007/10/02)
The compounds O,O-diethyl- and O,O-diisopropyl-S-benzylthiophosphite, 2-benzylthio-4,5-benzo-1,3,2-dioxaphospholane, diphenyl-S-benzylthiophosphinite, and S,S-dibenzylphenyldithiophosphonite were obtained.It was found that the thiophosphites enter into is
