Chemical Property of Phenyl dichlorophosphate
Chemical Property:
- Appearance/Colour:colorless transparent liquid
- Vapor Pressure:0.0541mmHg at 25°C
- Melting Point:-1 °C
- Refractive Index:n20/D 1.523(lit.)
- Boiling Point:242 °C at 760 mmHg
- Flash Point:99.1 °C
- PSA：36.11000
- Density:1.466 g/cm3
- LogP:3.65110
- Storage Temp.:2-8°C
- Sensitive.:Moisture Sensitive
- Water Solubility.:Decomposes
- XLogP3:2.8
- Hydrogen Bond Donor Count:0
- Hydrogen Bond Acceptor Count:2
- Rotatable Bond Count:2
- Exact Mass:209.9404218
- Heavy Atom Count:11
- Complexity:162
- Transport DOT Label:Corrosive
- Purity/Quality:
-
98% *data from raw suppliers
Phenyl Dichlorophosphate *data from reagent suppliers
Safty Information:
- Pictogram(s):
C
- Hazard Codes:C
- Statements:
34-37
- Safety Statements:
26-36/37/39-45
- MSDS Files:
-
SDS file from LookChem
Useful:
- Chemical Classes:Other Classes -> Organophosphates, Other
- Canonical SMILES:C1=CC=C(C=C1)OP(=O)(Cl)Cl
-
Uses
In organic synthesis for preparation of lactams, phosphate diesters and for oxidation reactions. Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime. Reagent for the preparation of phosphate diesters.
