[Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]

Base Information

• Chemical Name: [Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]
• CAS No.: 674322-80-6
• Molecular Formula: C₂₉H₂₇ClN₂Pd
• Molecular Weight: 545.42
• Mol file: 674322-80-6.mol

Synonyms:[Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]

Chemical Property of [Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)]

There total 1 articles about [Pd(CH₃)Cl(bis(3,5-(CH₃)2C₆H₃)acenaphthenequinonediimine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

chloromethyl(1,5-cyclooctadiene)palladium(II) + α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate (444798-21-4) → [Pd(CH3)Cl(bis(3,5-(CH3)2C6H3)acenaphthenequinonediimine)] (674322-80-6)

Guidance literature:

In dichloromethane; (Ar); using Schlenk techniques; addn. of 1.1 equiv. of C10H6(CNC6H3Me2)2to PdCl(COD)CH3 in CH2Cl2 at room temp. for 1 h according to: Milani,B. ; Marson, A.; Zangrando,E.; Mestroni,G.; Ernsting, J.M.; Elsevier, C. J.Inorg. Chim. Acta 2002, 327, 188-201; addn. of Et2O; pptn., elem. anal.;

DOI:10.1021/om7011858

Reference yield: 90.0%

silver(I) hexafluorophosphate (26042-63-7) + [Pd(CH3)Cl(bis(3,5-(CH3)2C6H3)acenaphthenequinonediimine)] (674322-80-6) + acetonitrile (75-05-8,26809-02-9) → [PdCl(acetonitrile)(bis(3,5-(CH3)2C6H3)acenaphthenequinonediimine)][PF6] (1019658-52-6)

Guidance literature:

In dichloromethane; acetonitrile; byproducts: AgCl; (Ar); using Schlenk techniques; dissolving of Pd(Me)Cl(C10H6(CNC6H3Me2)2) in min. amt. of CH2Cl2; addn. of soln. of AgPF6 (1.1 equiv.) in MeCN; pptn. for 30 min; filtration, concn. under vac., addn. of Et2O; pptn., elem. anal.;

DOI:10.1021/om7011858

Reference yield:

N,N'-bis(4-methoxyphenylimino)acenaphthene (153531-54-5,156398-77-5) + [Pd(CH3)Cl(bis(3,5-(CH3)2C6H3)acenaphthenequinonediimine)] (674322-80-6) → α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate (444798-21-4) + Pd(Me)Cl(bis(p-MeOC6H4-imino)acenaphthene)

Guidance literature:

In chloroform-d1; 1 equiv. of the free ligand was added to a CDCl3 soln. of Pd-complex at 20°C, reaction was monitored by (1)H NMR spectroscopy; equil. const. is given; (1)H NMR spectral data;

DOI:10.1021/om034370i

upstream raw materials:

α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate

Downstream raw materials:

α-diimine N,N′-bis(3,5-dimethylphenylimino)acenaphthenequinonate

(C₁₂H₆N₂(C₆H₄CF₃)2)Pd(CH₃)Cl

(C₁₂H₆N₂(C₆H₄Cl)2)Pd(CH₃)Cl

(C₁₂H₆N₂(C₆H₄CN)2)Pd(CH₃)Cl