1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

Base Information

Chemical Name:1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane
CAS No.:854737-55-6
Molecular Formula:C₁₆H₂₅BrO₃Si
Molecular Weight:373.362
Hs Code.:

Synonyms:1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

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Technology Process of 1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

There total 4 articles about 1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 854737-56-7
1-bromo-2-hydroxy-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

: 854737-55-6
1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 15h;
DOI:10.1016/j.tet.2005.03.074

Reference yield:

: 97-53-0
4-allylguaiacol

: 854737-55-6
1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / imidazole; DMAP / CH₂Cl₂ / 0 - 20 °C

2: 78 percent / NBS; H₂O / dimethylsulfoxide / 0 °C

3: 78 percent / Dess-Martin reagent / CH₂Cl₂ / 15 h / 20 °C

With 1H-imidazole; dmap; N-Bromosuccinimide; water; Dess-Martin periodane; In dichloromethane; dimethyl sulfoxide; 3: Dess-Martin oxidation;
DOI:10.1016/j.tet.2005.03.074

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 854737-55-6
1-bromo-2-keto-3-(3-methoxy-4-t-butyldimethylsilyloxy)phenyl propane

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / imidazole; DMAP / CH₂Cl₂ / 0 - 20 °C

2: 78 percent / NBS; H₂O / dimethylsulfoxide / 0 °C

3: 78 percent / Dess-Martin reagent / CH₂Cl₂ / 15 h / 20 °C

With 1H-imidazole; dmap; N-Bromosuccinimide; water; Dess-Martin periodane; In dichloromethane; dimethyl sulfoxide; 3: Dess-Martin oxidation;
DOI:10.1016/j.tet.2005.03.074