(2-Oxoheptyl)triphenylarsonium bromide

Base Information

• Chemical Name: (2-Oxoheptyl)triphenylarsonium bromide
• CAS No.: 121077-69-8
• Molecular Formula: Br*C₂₅H₂₈AsO
• Molecular Weight: 499.322
• Mol file: 121077-69-8.mol

Synonyms:(2-Oxoheptyl)triphenylarsonium bromide

Chemical Property of (2-Oxoheptyl)triphenylarsonium bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-Oxoheptyl)triphenylarsonium bromide

There total 1 articles about (2-Oxoheptyl)triphenylarsonium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1-bromoheptan-2-one (16339-93-8) + triphenyl-arsane (603-32-7) → (2-Oxoheptyl)triphenylarsonium bromide (121077-69-8)

Guidance literature:

In benzene; at 60 - 70 ℃; for 6h;

DOI:10.1055/s-1988-27772

Reference yield: 99.0%

benzaldehyde (100-52-7) + (2-Oxoheptyl)triphenylarsonium bromide (121077-69-8) → (E)-1-phenyloct-1-en-3-one (29478-39-5)

Guidance literature:

With water; potassium carbonate; In tetrahydrofuran; dichloromethane; at 25 ℃; for 5h;

DOI:10.1055/s-1988-27772

Reference yield: 87.0%

4-chlorobenzaldehyde (104-88-1) + (2-Oxoheptyl)triphenylarsonium bromide (121077-69-8) → (E)-1-(4-chlorophenyl)oct-1-en-3-one (100765-38-6)

Guidance literature:

With water; potassium carbonate; In tetrahydrofuran; dichloromethane; at 25 ℃; for 3h;

DOI:10.1055/s-1988-27772

upstream raw materials:

1-bromoheptan-2-one

triphenyl-arsane

Downstream raw materials:

(E)-1-(4-chlorophenyl)oct-1-en-3-one

(E)-1-phenyloct-1-en-3-one

(1E,3E)-1-Phenyl-deca-1,3-dien-5-one