cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)
• CAS No.: 55744-57-5
• Molecular Formula: C₃₆H₃₀Cl₂F₆P₄Ru
• Molecular Weight: 872.496
• Mol file: 55744-57-5.mol

Synonyms:cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)

Chemical Property of cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II)

There total 7 articles about cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.5%

tris(trifluorophosphine)bis(triphenylphosphine)ruthenium(0) (67840-34-0) → cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) (55744-57-5)

Guidance literature:

With HCl; In benzene; 2 equiv. HCl (sealed vessel, vac., 100°C, 12 h); solvent removal, recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1039/DT9780000889

Reference yield: 92.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) → cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) (55744-57-5)

Guidance literature:

With trifluorophosphane; In dichloromethane; sealed vessel (vac.); mixing of Ru-complex with slight stoich. excess ofPF3, slow warming to room temp., shaking (2 h); solvent removal, washing (hexane), recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1039/DT9780000895

Reference yield: 91.0%

cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)ruthenium(II) (56179-27-2,68736-36-7) → cis-dichlorobis(trifluorophosphine)bis(triphenylphosphine)ruthenium(II) (55744-57-5)

Guidance literature:

With HCl; In not given; 1 equiv. HCl (sealed vessel, vac., 60°C, 4 h); solvent removal, recrystn. (CH2Cl2/hexane);

DOI:10.1039/DT9780000889

upstream raw materials:

tris(trifluorophosphine)bis(triphenylphosphine)ruthenium⁽⁰⁾

tris(triphenylphosphine)ruthenium(II) chloride

N,N-dimethyl acetamide

cis-dihydrido(trifluorophosphine)tris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

tri-μ-chloro-chlorobis(trifluorophosphine)tris(triphenylphosphine)diruthenium(II)