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Tris(trifluorophosphine)bis(triphenylphosphine)ruthenium(0), also known as Ru(PF3)3(PPh3)2, is a transition metal complex that features ruthenium (Ru) as the central metal atom. It is a neutral, air-stable compound with a coordination number of 5, where three trifluorophosphine (PF3) ligands and two triphenylphosphine (PPh3) ligands surround the ruthenium center. This complex is of significant interest in organometallic chemistry and homogeneous catalysis, particularly in the field of olefin metathesis, where it serves as a catalyst to facilitate the redistribution of carbon-carbon double bonds in olefins. The electronic properties and steric environment provided by the ligands make this complex highly effective in promoting the metathesis reaction, which is crucial in the synthesis of various chemicals and materials.

67840-34-0

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67840-34-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 67840-34-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,7,8,4 and 0 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 67840-34:
(7*6)+(6*7)+(5*8)+(4*4)+(3*0)+(2*3)+(1*4)=150
150 % 10 = 0
So 67840-34-0 is a valid CAS Registry Number.

67840-34-0Relevant academic research and scientific papers

PHOSPHINE SUBSTITUTION AND PHOSPHINE INDUCED REDUCTIVE ELIMINATION REACTIONS: SYNTHESIS OF ZEROVALENT RUTHENIUM FLUOROPHOSPHINE COMPLEXES FROM HYDRIDO(ACETATO)TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Al-Ohaly, Abdul-Razzak,Head, Robert A.,Nixon, John F.

, p. 99 - 110 (1981)

Substitution of PPh3 from the bidentate acetatohydridoruthenium(II) complex RuH(CH3OCO)(PPh3)3 with various ligands, L, leads to unidentate acetatohydrido compounds with replacement of one, two or all PPh3 ligands depending on L (L = t=BuNC, PF2NMe2, P(OC

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