1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide

Base Information

• Chemical Name: 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide
• CAS No.: 81113-83-9
• Molecular Formula: C₁₇H₁₈O₄Se
• Molecular Weight: 365.288
• Mol file: 81113-83-9.mol

Synonyms:1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide

Chemical Property of 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide

There total 5 articles about 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tert.-butylhydroperoxide (75-91-2) + 2-(phenylselanyl)benzoic acid (25562-42-9) → 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide (81113-83-9)

Guidance literature:

In chloroform; for 5h; Ambient temperature;

DOI:10.1021/jo00133a008

Reference yield: 37.0%

tert.-butylhydroperoxide (75-91-2) + 2-(phenylselanyl)benzoyl chloride (81113-84-0) → 2-(phenylseleno)benzoic anhydride (81389-54-0) + 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one (81113-82-8) + 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide (81113-83-9)

Guidance literature:

With pyridine; In diethyl ether; at -15 ℃; for 120h; Title compound not separated from byproducts;

DOI:10.1021/jo00133a008

Reference yield: 8.2%

2-(phenylselanyl)benzoyl chloride (81113-84-0) → 2-(phenylseleno)benzoic anhydride (81389-54-0) + 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one (81113-82-8) + 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide (81113-83-9)

Guidance literature:

With pyridine; tert.-butylhydroperoxide; In diethyl ether; at -15 ℃; for 120h;

DOI:10.1021/jo00133a008

upstream raw materials:

tert.-butylhydroperoxide

2-(phenylselanyl)benzoyl chloride

2-(phenylselanyl)benzoic acid

Downstream raw materials:

2-carboxyphenyl phenyl selenone