phosphoric acid benzoylmethyl dimethyl ester

Base Information

• Chemical Name: phosphoric acid benzoylmethyl dimethyl ester
• CAS No.: 13392-51-3
• Molecular Formula: C₁₀H₁₃O₅P
• Molecular Weight: 244.184
• Mol file: 13392-51-3.mol

Synonyms:phosphoric acid benzoylmethyl dimethyl ester

Chemical Property of phosphoric acid benzoylmethyl dimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phosphoric acid benzoylmethyl dimethyl ester

There total 9 articles about phosphoric acid benzoylmethyl dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Dimethyl phosphite (868-85-9) + N-methyl-N-(1-phenylethylidene)amine N-oxide → phosphoric acid benzoylmethyl dimethyl ester (13392-51-3)

Guidance literature:

With tetrachloromethane; triethylamine; In tetrahydrofuran; at 25 ℃; for 5h; Reagent/catalyst; Solvent;

DOI:10.1021/acs.orglett.7b02852

Reference yield: 86.0%

2-<(dimethoxyphosphinyl)oxy>-2-phenyloxirane (132170-15-1) → phosphoric acid benzoylmethyl dimethyl ester (13392-51-3)

Guidance literature:

In benzene-d6; for 12h; Ambient temperature;

Reference yield: 71.0%

(1-hydroxy-2-oxo-2-phenylethyl)phosphonic acid dimethyl ester → phosphoric acid benzoylmethyl dimethyl ester (13392-51-3)

Guidance literature:

With potassium tert-butylate; In toluene; at 80 ℃; for 4h; Reagent/catalyst; Temperature; Inert atmosphere;

DOI:10.1016/j.tet.2016.05.067

upstream raw materials:

methyl phosphite

phenylglyoxal hydrate

α-bromophenylacetaldehyde

tetramethylammonium dimethyl phosphate