allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Base Information

Chemical Name:allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside
CAS No.:399036-29-4
Molecular Formula:C₆₈H₆₄Cl₃NO₂₂
Molecular Weight:1353.61
Hs Code.:

allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Synonyms:allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

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Chemical Property of allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

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Technology Process of allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

There total 7 articles about allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 77-76-9
2,2-dimethoxy-propane

: 399036-28-3
C₆₅H₆₀Cl₃NO₂₂

: 399036-29-4
allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: With 10-camphorsufonic acid; at 20 - 50 ℃; for 5h;
DOI:10.1016/S0008-6215(01)00213-0

Reference yield:

: 98-88-4
benzoyl chloride

: 399036-29-4
allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine / CH₂Cl₂ / 18 h / 20 °C

2: aq. CF₃CO₂H / CH₂Cl₂ / 0.5 h / 20 °C

3: 88 percent / AgOTf / CH₂Cl₂ / 3 h / -20 °C

4: 92 percent / AcCl / methanol / 26 h / 20 °C

5: 77 percent / (+/-)-CSA / 5 h / 20 - 50 °C

With pyridine; 10-camphorsufonic acid; silver trifluoromethanesulfonate; acetyl chloride; trifluoroacetic acid; In methanol; dichloromethane;
DOI:10.1016/S0008-6215(01)00213-0

Reference yield:

: 359669-13-9
allyl 2,3,6-tri-O-benzoyl-4-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-β-D-glucopyranoside

: 399036-29-4
allyl O-(2-deoxy-4,6-O-isopropylidene-2-trichloroacetamido-β-D-glucopyranosyl)-(1->3)-O-(2,4,6-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / AgOTf / CH₂Cl₂ / 3 h / -20 °C

2: 92 percent / AcCl / methanol / 26 h / 20 °C

3: 77 percent / (+/-)-CSA / 5 h / 20 - 50 °C

With 10-camphorsufonic acid; silver trifluoromethanesulfonate; acetyl chloride; In methanol; dichloromethane;
DOI:10.1016/S0008-6215(01)00213-0