dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Base Information

Chemical Name:dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside
CAS No.:1400594-72-0
Molecular Formula:C₂₉H₄₂Cl₃NO₉Si
Molecular Weight:683.098
Hs Code.:

Synonyms:dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Suppliers and Price of dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

There total 1 articles about dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 212713-50-3
dimethylthexylsilyl 4,6-O-benzylidene-2-[(2,2,2-trichloroethoxy)carbonylamino]-2-deoxy-β-D-glucopyranoside

: 123-76-2
levulinic acid

: 1400594-72-0
dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1021/ja3069962

Reference yield: 81.0%

: 1400594-72-0
dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

: 1400594-73-1
dimethylthexylsilyl 6-O-benzyl-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Guidance literature:: With triethylsilane; trifluorormethanesulfonic acid; In dichloromethane; at -78 ℃; Molecular sieve; Inert atmosphere;
DOI:10.1021/ja3069962

Reference yield:

: 1400594-72-0
dimethylthexylsilyl 4,6-O-benzylidene-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

: 1400595-03-0
dimethylthexylsilyl O-(2-O-allyloxycarbonyl-3-O-benzyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1→4)-6-O-benzyl-2-deoxy-3-O-levulinoyl-2-(2,2,2-trichloroethoxy)carbonylamino-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylsilane; trifluorormethanesulfonic acid / dichloromethane / -78 °C / Molecular sieve; Inert atmosphere

2.1: dichloromethane / 1 h / 20 °C / Molecular sieve; Inert atmosphere

2.2: 1 h / -20 °C / Molecular sieve; Inert atmosphere

With triethylsilane; trifluorormethanesulfonic acid; In dichloromethane;
DOI:10.1021/ja3069962