Technology Process of KCN-Triox1
There total 62 articles about KCN-Triox1 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
dirhodium tetraacetate;
In
dichloromethane;
at 23 ℃;
for 0.166667h;
Molecular sieve;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: trifluoroacetic acid / water; tetrahydrofuran / 5 h / Inert atmosphere
2: 4-methylmorpholine N-oxide; osmium(VIII) oxide / acetone; water / 12 h / 25 °C / Inert atmosphere
3: triethylamine; dmap / dichloromethane / 5 h / 0 - 25 °C / Inert atmosphere
4: potassium carbonate / 1 h / Inert atmosphere
5: 4-methylmorpholine N-oxide; tetrapropylammonium perruthennate / 1 h / Inert atmosphere
With
dmap; osmium(VIII) oxide; tetrapropylammonium perruthennate; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine; trifluoroacetic acid;
In
tetrahydrofuran; dichloromethane; water; acetone;
2: |Upjohn Dihydroxylation;
DOI:10.1002/anie.201410369
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / acetone; water / 12 h / 25 °C / Inert atmosphere
2: triethylamine; dmap / dichloromethane / 5 h / 0 - 25 °C / Inert atmosphere
3: potassium carbonate / 1 h / Inert atmosphere
4: 4-methylmorpholine N-oxide; tetrapropylammonium perruthennate / 1 h / Inert atmosphere
With
dmap; osmium(VIII) oxide; tetrapropylammonium perruthennate; potassium carbonate; 4-methylmorpholine N-oxide; triethylamine;
In
dichloromethane; water; acetone;
1: |Upjohn Dihydroxylation;
DOI:10.1002/anie.201410369
