[tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane

Base Information

• Chemical Name: [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane
• CAS No.: 258526-24-8
• Molecular Formula: C₂₅H₄₈AsClN₂Si
• Molecular Weight: 515.13
• Mol file: 258526-24-8.mol

Synonyms:[tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane

Chemical Property of [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane

There total 2 articles about [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

2,4,6-Tri-tert-butylaniline (961-38-6) + [tert-butyl(trimethylsilyl)amino]dichloroarsane (258526-22-6) → [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane (258526-24-8)

Guidance literature:

With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; for 1h;

DOI:10.1002/(sici)1099-0682(200001)2000:1<165::aid-ejic165>3.0.co;2-i

Reference yield:

trimethyl(tert-butylamino)silane (5577-67-3) → [tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane (258526-24-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 81 percent / AsCl₃; nBuLi / diethyl ether; hexane / -78 - 20 °C

2: 60 percent / nBuLi / diethyl ether; hexane / 1 h / -78 - 20 °C

With n-butyllithium; arsenic trichloride; In diethyl ether; hexane; 1: Substitution / 2: Condensation;

DOI:10.1002/(sici)1099-0682(200001)2000:1<165::aid-ejic165>3.0.co;2-i

Reference yield: 75.0%

[tert-butyl(trimethylsilyl)amino]chloro(2,4,6-tri-tert-butylphenylamino)arsane (258526-24-8) → [tert-butyl(trimethylsilyl)amino](2,4,6-tri-tert-butylphenylimino)arsane

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In hexane; at 20 ℃; for 1h;

DOI:10.1002/(sici)1099-0682(200001)2000:1<165::aid-ejic165>3.0.co;2-i

upstream raw materials:

2,4,6-Tri-tert-butylaniline

[tert-butyl(trimethylsilyl)amino]dichloroarsane

trimethyl(tert-butylamino)silane