N-tert-Butyltrimethylsilylamine

Base Information

• Chemical Name: N-tert-Butyltrimethylsilylamine
• CAS No.: 5577-67-3
• Molecular Formula: C7H19 N Si
• Molecular Weight: 145.32
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70204331
• Nikkaji Number: J364.746C
• Wikidata: Q83077772
• Mol file: 5577-67-3.mol

Synonyms:N-tert-Butyltrimethylsilylamine;5577-67-3;tert-Butylaminotrimethylsilane;2-methyl-N-trimethylsilylpropan-2-amine;TERT-BUTYL(TRIMETHYLSILYL)AMINE;tert-C4H9NHSi(CH3)3;tert-Butylamine, TMS derivative;EC 628-649-0;N-(Trimethylsilyl)-tert-butylamine;SCHEMBL479296;N-tert.-butyltrimethylsilylamin;Silanamine, N-(1,1-dimethylethyl)-1,1,1-trimethyl-;tert-Butyl-trimethylsilanyl-amine;DTXSID70204331;MFCD00054891;N-tert-Butyltrimethylsilylamine, 98%;AKOS025295466;N-(tert-Butyl)(trimethyl)silanamine #;N-(tert-Butyl)-N-(trimethylsilyl)amine;BS-23810;F71345;EN300-7366453

Chemical Property of N-tert-Butyltrimethylsilylamine

Chemical Property:

• Vapor Pressure: 16.3mmHg at 25°C
• Refractive Index: n20/D 1.406(lit.)
• Boiling Point: 118.9°Cat760mmHg
• Flash Point: 26.7°C
• PSA: 12.03000
• Density: 0.77g/cm³
• LogP: 2.60030
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 145.128676145
• Heavy Atom Count: 9
• Complexity: 86.1

Purity/Quality:

99.9% ^*data from raw suppliers

N-tert-Butyltrimethylsilylamine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 1734528
• Hazard Codes: C
• Statements: 10-34
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)N[Si](C)(C)C
• Uses: N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides and the facile synthesis of N-alkylaminomethylphosphonates.

Technology Process of N-tert-Butyltrimethylsilylamine

There total 4 articles about N-tert-Butyltrimethylsilylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(di-tert-butylamino){(2,4,6-triisopropylphenyl)phosphino}boron fluoride (112438-27-4) + lithium tert-butyl-trimethylsilylamide (18270-42-3) → 2,4-bis(di-tert-butylamino)-1,3-bis(2,4,6-triisopropylphenyl)-1,3,2,4-diphosphadiboretane (112438-28-5) + trimethyl(tert-butylamino)silane (5577-67-3) + lithium fluoride (7789-24-4)

Guidance literature:

In benzene; under N2 or Ar or in vac., reflux for 4 days; solid filtered off, solvent of filtrate evapd., crystn. from toluene at -78°C; elem. anal.;

Reference yield: 65.0%

{{bis(trimethylsilyl)methyl}phosphino}fluoro(2,2,6,6-tetramethylpiperidino)borane (112438-25-2) + lithium tert-butyl-trimethylsilylamide (18270-42-3) → 1,3-bis{bis(trimethylsilyl)methyl}-2,4-bis(2,2,6,6-tetramethylpiperidino)-1,3,2,4-diphosphadiboretane (112438-26-3) + trimethyl(tert-butylamino)silane (5577-67-3) + lithium fluoride (7789-24-4)

Guidance literature:

In benzene; under N2 or Ar or in vac., reflux for 4 days; solid filtered off, solvent of filtrate evapd., crystn. from toluene at -78°C; elem. anal.;

Reference yield:

2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan (80431-36-3) + tert-butylamine (75-64-9) → Benzophenone imine (1013-88-3) + trimethyl(tert-butylamino)silane (5577-67-3) + tert-Butylaminodimethylsilyl-bis(trimethylsilyl)methan

Guidance literature:

In diethyl ether; at 100 ℃; for 10h;

upstream raw materials:

picoline

lithium tert-butyl-trimethylsilylamide

2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan

tert-butylamine

Downstream raw materials:

2-(tert-butylamino)-1-phenylethan-1-ol

2-(tert-butylamino)-2-phenylethanol

{t-butyl(trimethylsilyl)amino}(diisopropylamino)fluoroborane

lithium fluoride

Refernces

• 1、 Wiberg, N.,Preiner, G.,Wagner, G.,Koepf, H.. "Reactivity of the Labile Silaethene Me2Si=C(SiMe3)2, Stored as Ph2C=NSiMe3 Adducts". . p. 1062 - 1074. Retrieved 2007/10/02.