5577-67-3

Usage

Uses

Used in Chemical Synthesis:
N-TERT-BUTYLTRIMETHYLSILYLAMINE is used as a reagent for the preparation of selenium and tellurium chalcogenides. It plays a crucial role in the synthesis process due to its ability to react with specific compounds, leading to the formation of these chalcogenides.
Used in Pharmaceutical Industry:
N-TERT-BUTYLTRIMETHYLSILYLAMINE is used as a reagent for the facile synthesis of N-alkylaminomethylphosphonates. These compounds have potential applications in the development of new pharmaceuticals, particularly in the area of medicinal chemistry.

InChI:InChI=1/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3

Upstream product

• 112438-25-2 {{bis(trimethylsilyl)methyl}phosphino}fluoro(2,2,6,6-tetramethylpiperidino)borane 
• 18270-42-3 lithium tert-butyl-trimethylsilylamide 
• 112438-27-4 (di-tert-butylamino){(2,4,6-triisopropylphenyl)phosphino}boron fluoride 
• 80431-36-3 2,2-Dimethyl-4,4-diphenyl-1,3,3-tris(trimethylsilyl)-1-aza-2-silacyclobutan 
• 75-64-9 tert-butylamine 
• 108-89-4 picoline 

Downstream Products

• 13435-12-6 N-Trimethylsilylacetamide 
• 72886-50-1 (tert-butyl(trimethylsilyl)amino)chloro(pentafluorophenyl)borane 
• 135629-94-6 N-tert-butyl-As,As-di-p-tolylarsinous amide 
• 125910-89-6 tert-butylaminochlorophenylarsine 
• 135629-91-3 C₁₀H₁₅AsBrN 
• 135629-90-2 C₁₀H₁₅AsIN 
• 135629-92-4 C₁₁H₁₇AsClN 
• 125910-92-1 C₁₁H₁₇AsClNO 
• 135629-89-9 N-tert-butyl-As-m-tolylarsonamidous bromide 
• 5894-65-5 N-t-butylbenzamide 
• 107264-43-7 tert-Butyl-(2-methyl-5-phenyl-2,4-dihydro-[1,2,4,3]triazaphosphol-3-yl)-trimethylsilanyl-amine 
• 107264-87-9 (5-Benzyl-2-methyl-3-thioxo-3,4-dihydro-2H-3λ⁵-[1,2,4,3]triazaphosphol-3-yl)-(2,2-dimethyl-propyl)-amine 
• 107264-72-2 tert-Butyl-(2-methyl-5-phenyl-3-thioxo-3,4-dihydro-2H-3λ⁵-[1,2,4,3]triazaphosphol-3-yl)-trimethylsilanyl-amine 
• 14467-32-4 2-(tert-butylamino)-1-phenylethan-1-ol 

Relevant academic research and scientific papers

Synthesis and Structures of New 1,3,2,4-Diphosphadiboretanes

Three methods have been devised to prepare new diphosphadiboretanes: a) Base-induced hydrogen halide elimination from (amino)phosphinoboron halides precursors, b) tris(trimethylsilyl)phosphane elimination from R2N-B2 intermediates prepared in situ from combination of R2N-B(Cl)-P(SiMe3)2 and LiP(SiMe3)2, and organylphosphane elimination from aminobis(organylphosphino)boranes R2N-B(PHR')2.The molecular structures of three new 1,3,2,4-diphosphadiboretanes (3, 4a, 4c) were determined by X-ray diffractometry.These are characterized by a planar four-membered B2P2 ring with the phosphorus substituents in trans positions.Their BP bomnds represent single bond distances.Experimental results are compared with MNDO III calculations which reveal a low barrier (ΔE = 5 kcal/mol) for the dimerization of the boraphosphane H2N-B=PMe to the diphospadiboretane (H2N-BPMe)2.

Reactivity of the Labile Silaethene Me2Si=C(SiMe3)2, Stored as Ph2C=NSiMe3 Adducts

Silaethene Me2Si=C(SiMe3)2 (1), stored as Ph2C=NSiMe3 adducts and regenerated from the adducts at about 100 deg C as a reaction intermediate, combines with reactants a-b (e.g.HO-H, RO-H, RCOO-H, RS-H, RHN-H, Ph2CN-H, RO-SiR3, R2N-SiR3, Ph2CN-SiR3, Cl-GeR3, Cl-SnR3) with insertion into the a-b bond, with a=b (e.g.O=CPh2, Me3SiN=CPh2, CH2=CHOMe, cis-piperylene), a=b=c (e.g.RN=N=N, O=N=N), a=b-c=d (e.g. butadiene, isoprene, trans-piperylene, 2,3-dimethylbutadiene, cyclopentadiene, anthracene, benzophenone, N-trimethylsilylbenzophenoneimine) under -, - as well as -c ycloaddition and with a=b-c-H (e.g. propene, butenes, isoprene, 2,3-dimethylbutadiene, acetone) under ene reaction.According to relative reaction rates, insertion and -cycloadditions seem to proceed in two reaction steps, whereas -cycloadditions and ene reactions with organic dienes and enes obviously are one step reactions.For reactivities cf.Table I. - Key words: Silaethene Me2Si=C(SiMe3)2, Insertions, Cycloadditions, Relative Reactivities