Technology Process of dichlorocarbonyltris(triphenylphosphine)osmium(II)
There total 4 articles about dichlorocarbonyltris(triphenylphosphine)osmium(II) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
hydrogenchloride; triphenylphosphine;
In
benzene;
anhyd. HCl gas bubbling through a soln. of Os complex and PPh3 in benzene for 5 min, stirring at ambient temp. for 11 h under N2, evapg., ppt. filtering off, washing with EtOH and Et2O; identified by elem. anal., IR and NMR spectra;
DOI:10.1016/S0020-1693(00)83666-X
- Guidance literature:
-
With
hydrogenchloride; formaldehyd; triphenylphosphine;
In
2-methoxy-ethanol;
PPh3, concd. aq. HCl and aq. CH2O adding to a suspn. of OsCl2(PPh3)3 in2-methoxyethanol, mixt. refluxing for 4 h under N2, ppt. filtering off and washing with EtOH and Et2O; identified by elem. anal., IR and NMR spectra;
DOI:10.1016/S0020-1693(00)83666-X
- Guidance literature:
-
With
hydrogenchloride; formaldehyd; triphenylphosphine;
In
2-methoxy-ethanol;
concd. HCl and aq. CH2O adding to a mixt. of Os complex and PPh3 in 2-methoxyethanol, refluxing for 7 h under N2, cooling, ppt. filtering off, washing with EtOH and Et2O; identified by elem. anal., IR and NMR spectra;
DOI:10.1016/S0020-1693(00)83666-X
