4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

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Chemical Name:4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline
CAS No.:182944-04-3
Molecular Formula:C₅₁H₆₄N₂O₂Si
Molecular Weight:765.167
Hs Code.:

Synonyms:4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

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Chemical Property of 4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

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Technology Process of 4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

There total 10 articles about 4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 104465-98-7
(3-bromoprop-1-yn-1-yl)triisopropylsilane

: 182943-92-6
4,7-di-(n-hexyl)-9-(p-hydroxyphenyl)-2-[4-(2-propynyloxy)phenyl]-1,10-phenanthroline

: 182944-04-3
4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 50 ℃; for 19h;
DOI:10.1016/0040-4020(96)00613-8

Reference yield:

: 14774-77-7
p-methoxyphenyllithium

: 182944-04-3
4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 5 steps

1: 49 percent / MnO₂ / H₂O

2: MnO₂ / H₂O

3: 100 percent / PyHCl / 210 °C

4: 42 percent / DBU / tetrahydrofuran; CH₂Cl₂ / 3 h / Heating

5: 96 percent / K₂CO₃ / dimethylformamide / 19 h / 50 °C

With manganese(IV) oxide; pyridine hydrochloride; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(96)00613-8

Reference yield:

: 88-74-4
2-nitro-aniline

: 182944-04-3
4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 8 steps

1: 42 percent / H₃AsO₄, H₃PO₄ / 120 °C

2: 92 percent / SnCl₂, EtOH

3: 46 percent / H₃AsO₄, H₃PO₄ / 120 °C

4: 49 percent / MnO₂ / H₂O

5: MnO₂ / H₂O

6: 100 percent / PyHCl / 210 °C

7: 42 percent / DBU / tetrahydrofuran; CH₂Cl₂ / 3 h / Heating

8: 96 percent / K₂CO₃ / dimethylformamide / 19 h / 50 °C

With manganese(IV) oxide; ethanol; phosphoric acid; pyridine hydrochloride; orthoarsenic acid; potassium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tin(ll) chloride; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(96)00613-8