Silane, (3-bromo-1-propynyl)tris(1-methylethyl)-

Base Information

• Chemical Name: Silane, (3-bromo-1-propynyl)tris(1-methylethyl)-
• CAS No.: 104465-98-7
• Molecular Formula: C12H23BrSi
• Molecular Weight: 275.304
• Mol file: 104465-98-7.mol

Synonyms:

Chemical Property of Silane, (3-bromo-1-propynyl)tris(1-methylethyl)-

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Silane, (3-bromo-1-propynyl)tris(1-methylethyl)-

There total 1 articles about Silane, (3-bromo-1-propynyl)tris(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

triisopropylsilyl trifluoromethanesulfonate (80522-42-5) + propargyl bromide (106-96-7) → (3-bromoprop-1-yn-1-yl)triisopropylsilane (104465-98-7)

Guidance literature:

propargyl bromide; With sodium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.0833333h;

triisopropylsilyl trifluoromethanesulfonate; In tetrahydrofuran; diethyl ether; at -40 ℃; for 1h;

DOI:10.1002/chem.202004843

Reference yield: 96.0%

methyl 3-azido-4-hydroxybenzoate (1393745-17-9) + (3-bromoprop-1-yn-1-yl)triisopropylsilane (104465-98-7) → C20H29N3O3Si

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 4h; Inert atmosphere;

Reference yield: 95.0%

C18H28BO2(1-)*Li(1+) + (3-bromoprop-1-yn-1-yl)triisopropylsilane (104465-98-7) → (Z)-triisopropyl(5-phenylpent-4-en-1-yn-1-yl)silane

Guidance literature:

With iron(III) chloride; magnesium bromide; In tetrahydrofuran; at -78 - 0 ℃; for 1h; stereoselective reaction; Inert atmosphere;

DOI:10.1039/d0ob00357c

upstream raw materials:

triisopropylsilyl trifluoromethanesulfonate

propargyl bromide

Downstream raw materials:

Triphenyl-(3-triisopropylsilanyl-prop-2-ynylidene)-λ⁵-phosphane

4,7-Dihexyl-2-(4-prop-2-ynyloxy-phenyl)-9-[4-(3-triisopropylsilanyl-prop-2-ynyloxy)-phenyl]-[1,10]phenanthroline