3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Base Information

Chemical Name:3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate
CAS No.:1203584-66-0
Molecular Formula:C₂₆H₂₆F₃N₃O₁₂S
Molecular Weight:661.567
Hs Code.:

Synonyms:3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Suppliers and Price of 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

There total 6 articles about 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: C₁₈H₂₂N₂O₁₂S

: 61881-19-4
2,2,2-trifluoro-N-phenyl-acetimidoyl chloride

: 1203584-66-0
3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Guidance literature:: With caesium carbonate; In tetrahydrofuran; dichloromethane; at 0 - 20 ℃; for 1h; optical yield given as %de; Inert atmosphere;
DOI:10.1080/07328300903105108

Reference yield:

: 114297-26-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-{[(4-methoxyphenyl)methylidene]amino}-D-glucopyranose

: 1203584-66-0
3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Guidance literature:: Multi-step reaction with 6 steps

1: ammonia / tetrahydrofuran; methanol / 1.5 h / 0 °C

2: 1H-imidazole / dichloromethane / 2 h / 20 °C / Inert atmosphere

3: hydroxylamine hydrochloride / tetrahydrofuran; water / 0.75 h / 20 °C / Inert atmosphere

4: triethylamine / dichloromethane / 5 h / 20 °C / Inert atmosphere

5: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

6: caesium carbonate / tetrahydrofuran; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; hydroxylamine hydrochloride; tetrabutyl ammonium fluoride; ammonia; caesium carbonate; acetic acid; triethylamine; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1080/07328300903105108

Reference yield:

: 1203584-64-8
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose

: 1203584-66-0
3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

2: caesium carbonate / tetrahydrofuran; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

With tetrabutyl ammonium fluoride; caesium carbonate; acetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1080/07328300903105108