methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

Base Information

Chemical Name:methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside
CAS No.:1203584-56-8
Molecular Formula:C₁₉H₂₄N₂O₁₂S
Molecular Weight:504.472
Hs Code.:

Synonyms:methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

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Technology Process of methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

There total 7 articles about methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 67-56-1
methanol

: 1203584-66-0
3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranosyl N-(phenyl)trifluoroacetimidate

: 1203584-56-8
methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -30 - 0 ℃; for 2h; Inert atmosphere;
DOI:10.1080/07328300903105108

Reference yield:

: 1203584-64-8
tert-butyldiphenylsilyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranose

: 1203584-56-8
methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere

2: caesium carbonate / tetrahydrofuran; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

3: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 2 h / -30 - 0 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; caesium carbonate; acetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1080/07328300903105108

Reference yield:

: C₁₈H₂₂N₂O₁₂S

: 1203584-56-8
methyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzenesulfonylamino)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: caesium carbonate / tetrahydrofuran; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 2 h / -30 - 0 °C / Inert atmosphere

With trimethylsilyl trifluoromethanesulfonate; caesium carbonate; In tetrahydrofuran; dichloromethane;
DOI:10.1080/07328300903105108