10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

Base Information

Chemical Name:10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione
CAS No.:109492-87-7
Molecular Formula:C₁₈H₂₄O₄
Molecular Weight:304.386
Hs Code.:

Synonyms:10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

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Chemical Property of 10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

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Technology Process of 10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

There total 15 articles about 10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 109492-86-6
6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

: 109492-87-7
10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethanol; for 0.75h; under 760 Torr;

Reference yield:

: 104-01-8
4-Methoxyphenylacetic acid

: 109492-87-7
10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

Guidance literature:: Multi-step reaction with 12 steps

1: HCl

2: 96.5 percent / sodamide / liquid ammonia; tetrahydrofuran / 1 h / -33 °C

3: 32 g / AlCl₃ / benzene / 7 h / Heating

4: 82 percent / K₂CO₃, KI / butan-2-one / Heating

5: 84 percent / 2M-aq. NaOH / ethanol / 1 h / Heating

6: thionyl chloride / Ambient temperature

7: 86 percent / 1.) Mg; 2.) CdCl₂ / 1.) ether, reflux, 1 h; 2.) rt., 15 min then benzene, reflux, 1 h

8: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

9: 0.77 g / m-chloroperbenzoic acid, K₂CO₃

10: 71 percent / BF₃*OEt₂

11: 60 percent / m-chloroperbenzoic acid

12: 100 percent / H₂ / 10percent Pd-C / aq. ethanol / 0.75 h / 760 Torr

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; aluminium trichloride; thionyl chloride; boron trifluoride diethyl etherate; hydrogen; sodium hydride; potassium carbonate; sodium amide; magnesium; 3-chloro-benzenecarboperoxoic acid; potassium iodide; cadmium(II) chloride; palladium on activated charcoal; In tetrahydrofuran; ethanol; ammonia; butanone; benzene;

Reference yield:

: 23786-14-3
4-methoxy-phenyl acetic acid methyl ester

: 109492-87-7
10,11-epoxy-6-(4-hydroxyphenyl)-6-methylundecan-3,7-dione

Guidance literature:: Multi-step reaction with 11 steps

1: 96.5 percent / sodamide / liquid ammonia; tetrahydrofuran / 1 h / -33 °C

2: 32 g / AlCl₃ / benzene / 7 h / Heating

3: 82 percent / K₂CO₃, KI / butan-2-one / Heating

4: 84 percent / 2M-aq. NaOH / ethanol / 1 h / Heating

5: thionyl chloride / Ambient temperature

6: 86 percent / 1.) Mg; 2.) CdCl₂ / 1.) ether, reflux, 1 h; 2.) rt., 15 min then benzene, reflux, 1 h

7: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

8: 0.77 g / m-chloroperbenzoic acid, K₂CO₃

9: 71 percent / BF₃*OEt₂

10: 60 percent / m-chloroperbenzoic acid

11: 100 percent / H₂ / 10percent Pd-C / aq. ethanol / 0.75 h / 760 Torr

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; aluminium trichloride; thionyl chloride; boron trifluoride diethyl etherate; hydrogen; sodium hydride; potassium carbonate; sodium amide; magnesium; 3-chloro-benzenecarboperoxoic acid; potassium iodide; cadmium(II) chloride; palladium on activated charcoal; In tetrahydrofuran; ethanol; ammonia; butanone; benzene;