6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

Base Information

Chemical Name:6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione
CAS No.:109492-86-6
Molecular Formula:C₂₅H₃₀O₄
Molecular Weight:394.511
Hs Code.:

Synonyms:6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

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Chemical Property of 6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

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Technology Process of 6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

There total 13 articles about 6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 109492-84-4
6-(4-benzyloxyphenyl)-6-methylundec-10-ene-3,7-dione

: 109492-86-6
6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid;

Reference yield:

: 104-01-8
4-Methoxyphenylacetic acid

: 109492-86-6
6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

Guidance literature:: Multi-step reaction with 11 steps

1: HCl

2: 96.5 percent / sodamide / liquid ammonia; tetrahydrofuran / 1 h / -33 °C

3: 32 g / AlCl₃ / benzene / 7 h / Heating

4: 82 percent / K₂CO₃, KI / butan-2-one / Heating

5: 84 percent / 2M-aq. NaOH / ethanol / 1 h / Heating

6: thionyl chloride / Ambient temperature

7: 86 percent / 1.) Mg; 2.) CdCl₂ / 1.) ether, reflux, 1 h; 2.) rt., 15 min then benzene, reflux, 1 h

8: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

9: 0.77 g / m-chloroperbenzoic acid, K₂CO₃

10: 71 percent / BF₃*OEt₂

11: 60 percent / m-chloroperbenzoic acid

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; aluminium trichloride; thionyl chloride; boron trifluoride diethyl etherate; sodium hydride; potassium carbonate; sodium amide; magnesium; 3-chloro-benzenecarboperoxoic acid; potassium iodide; cadmium(II) chloride; In tetrahydrofuran; ethanol; ammonia; butanone; benzene;

Reference yield:

: 23786-14-3
4-methoxy-phenyl acetic acid methyl ester

: 109492-86-6
6-(4-benzyloxyphenyl)-10,11-epoxy-6-methylundecan-3,7-dione

Guidance literature:: Multi-step reaction with 10 steps

1: 96.5 percent / sodamide / liquid ammonia; tetrahydrofuran / 1 h / -33 °C

2: 32 g / AlCl₃ / benzene / 7 h / Heating

3: 82 percent / K₂CO₃, KI / butan-2-one / Heating

4: 84 percent / 2M-aq. NaOH / ethanol / 1 h / Heating

5: thionyl chloride / Ambient temperature

6: 86 percent / 1.) Mg; 2.) CdCl₂ / 1.) ether, reflux, 1 h; 2.) rt., 15 min then benzene, reflux, 1 h

7: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

8: 0.77 g / m-chloroperbenzoic acid, K₂CO₃

9: 71 percent / BF₃*OEt₂

10: 60 percent / m-chloroperbenzoic acid

With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; aluminium trichloride; thionyl chloride; boron trifluoride diethyl etherate; sodium hydride; potassium carbonate; sodium amide; magnesium; 3-chloro-benzenecarboperoxoic acid; potassium iodide; cadmium(II) chloride; In tetrahydrofuran; ethanol; ammonia; butanone; benzene;