[2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)

Base Information

• Chemical Name: [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)
• CAS No.: 1501943-18-5
• Molecular Formula: C₂₃H₂₂N₄Ni
• Molecular Weight: 413.144
• Mol file: 1501943-18-5.mol

Synonyms:[2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)

Chemical Property of [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)

There total 2 articles about [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

[(C4H7)NiCl]2 (12145-60-7) + bis-N-phenyl-2-cyano-β-diketiminate → [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel(II) (1501943-18-5)

Guidance literature:

bis-N-phenyl-2-cyano-β-diketiminate; With potassium hydride; In tetrahydrofuran; for 12h;

[(C₄H₇)NiCl]2; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1021/om400847b

Reference yield:

acetylacetone (123-54-6,81235-32-7) + anthranilic acid nitrile (1885-29-6) → [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel(II) (1501943-18-5)

Guidance literature:

Multi-step reaction with 2 steps

1.1: toluene-4-sulfonic acid / toluene / 24 h / Reflux; Dean-Stark

2.1: potassium hydride / tetrahydrofuran / 12 h

2.2: 4 h / 20 °C

With potassium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; toluene;

DOI:10.1021/om400847b

Reference yield: 82.0%

[2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel(II) (1501943-18-5) + tris(pentafluorophenyl)borate (1109-15-5) → [2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel(II) 2[tris(pentafluorophenyl)boron] (1501943-23-2)

Guidance literature:

In toluene; for 0.166667h;

DOI:10.1021/om400847b

upstream raw materials:

[(C₄H₇)NiCl]2

acetylacetone

anthranilic acid nitrile

Downstream raw materials:

[2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II) 2[tris(pentafluorophenyl)boron]