7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester

Base Information

• Chemical Name: 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester
• CAS No.: 283586-98-1
• Molecular Formula: C₈H₅ClF₆N₂O₃
• Molecular Weight: 326.583
• Mol file: 283586-98-1.mol

Synonyms:7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester

Chemical Property of 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester

There total 1 articles about 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-chloro-4,4,5,5,6,6-hexafluoro-3-oxo-hexanoic acid ethyl ester → diazoacetic acid ethyl ester (623-73-4) + 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester (283586-98-1)

Guidance literature:

With polyfluoroalkanesulfonyl azide; In diethyl ether; at 0 ℃; for 0.5h;

DOI:10.1016/S0040-4020(01)00183-1

Reference yield: 64.0%

benzonitrile (100-47-0) + 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester (283586-98-1) → 2-Phenyl-4-carbethoxy-5-(3-chloro-1,1,2,2,3,3-hexafluoropropyl)oxazole

Guidance literature:

dirhodium tetraacetate; at 80 - 90 ℃;

DOI:10.1016/S0022-1139(99)00306-1

Reference yield: 52.0%

3-Methylbenzonitrile (620-22-4) + 7-Chloro-4,4,5,5,6,6-hexafluoro-2-diazo-3-oxoheptanoic acid ethyl ester (283586-98-1) → 4-Carbethoxy-2-(3-m-tolyl)-5-(3-chloro-1,1,2,2,3,3-hexafluoropropyl)oxazole

Guidance literature:

dirhodium tetraacetate; at 80 - 90 ℃;

DOI:10.1016/S0022-1139(99)00306-1