methyl 3-(4-methoxy-3,6-dioxocyclohexa-1,4-dien-1-yl)propanoate

Base Information

• Chemical Name: methyl 3-(4-methoxy-3,6-dioxocyclohexa-1,4-dien-1-yl)propanoate
• CAS No.: 67566-09-0
• Molecular Formula: C₁₁H₁₂O₅
• Molecular Weight: 224.213
• Mol file: 67566-09-0.mol

Synonyms:NSC 324654

Chemical Property of methyl 3-(4-methoxy-3,6-dioxocyclohexa-1,4-dien-1-yl)propanoate

Chemical Property:

• Vapor Pressure: 2.91E-05mmHg at 25°C
• Boiling Point: 356.5°Cat760mmHg
• Flash Point: 158.8°C
• Density: 1.23g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl 3-(4-methoxy-3,6-dioxocyclohexa-1,4-dien-1-yl)propanoate

There total 2 articles about methyl 3-(4-methoxy-3,6-dioxocyclohexa-1,4-dien-1-yl)propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methanol (67-56-1) + 3,4-methoxycinnamic acid (2107-70-2) → 2-methoxy-5-(2-carbomethoxyethyl)-1,4-benzoquinone (67566-09-0)

Guidance literature:

With boron trifluoride diethyl etherate; thallium(III) trifluoroacetate; Yield given. Multistep reaction; 1.) TFA, methylene chloride, 0 deg C, 1 min;

DOI:10.1021/ja00413a013

Reference yield:

→ 2-methoxy-5-(2-carbomethoxyethyl)-1,4-benzoquinone (67566-09-0)

Guidance literature:

Saeure 15a, 1) Tl(III)-trifluoracetat, 2) Me.;

DOI:10.1021/jo00412a059

upstream raw materials:

methanol

3,4-methoxycinnamic acid