1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

Base Information

Chemical Name:1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose
CAS No.:77015-97-5
Molecular Formula:C₁₇H₂₀ClN₃O₆
Molecular Weight:397.815
Hs Code.:

Synonyms:1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

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Chemical Property of 1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

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Technology Process of 1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

There total 1 articles about 1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-24-7
acetic anhydride

: 77015-96-4
1,6-Anhydro-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-β-D-glucopyranose

: 1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-β-D-glucopyranose

: 77015-97-5
1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

Guidance literature:: With sulfuric acid; In acetic acid; for 20h; Yield given. Yields of byproduct given; Ambient temperature;

Reference yield: 95.0%

: 77015-97-5
1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

: 77015-98-6
6-O-Acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranosylbromid

Guidance literature:: With titanium(IV) bromide; In dichloromethane; ethyl acetate; toluene; for 20h;

Reference yield:

: 77015-97-5
1,6-Di-O-acetyl-2-azido-3-O-benzyl-4-chlor-2,4-didesoxy-α-D-glucopyranose

: 77016-06-9
4-O-(2'-Amino-4'-chlor-2',4'-didesoxy-α-D-glucopyranosyl)-2-desoxy-6-O-(3''-desoxy-4''-C-methyl-3''-methylamino-β-L-arabinopyranosyl)-D-streptamin

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / TiBr₄ / CH₂Cl₂; toluene; ethyl acetate / 20 h

2: 95 percent / N(C₂H₅)4Cl / acetonitrile / 0.17 h / Ambient temperature

3: 1.) Drierite, molecular sieve 4 Angstroem, Hg(CN)2 / 1.)CH₃CN, PhMe, 60 deg C, 2.) PhMe, CH₃CN, reflux

4: NaOCH₃ / acetonitrile; methanol

5: H₂, 3percent HCl / 10percent Pd/C / dioxane; acetic acid

With hydrogenchloride; calcium sulfate; 4 A molecular sieve; tetraethylammonium chloride; hydrogen; sodium methylate; mercury(II) cyanide; titanium(IV) bromide; palladium on activated charcoal; In 1,4-dioxane; methanol; dichloromethane; acetic acid; ethyl acetate; toluene; acetonitrile;