PdI₂(bis(diphenylphosphino)methane)

Base Information

Chemical Name:PdI₂(bis(diphenylphosphino)methane)
CAS No.:77462-40-9
Molecular Formula:C₂₅H₂₂I₂P₂Pd
Molecular Weight:744.626
Hs Code.:

PdI<sub>2</sub>(bis(diphenylphosphino)methane)

Synonyms:PdI₂(bis(diphenylphosphino)methane)

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Chemical Property of PdI₂(bis(diphenylphosphino)methane)

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Technology Process of PdI₂(bis(diphenylphosphino)methane)

There total 14 articles about PdI₂(bis(diphenylphosphino)methane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 38425-01-3
(bis(diphenylphosphino)methane)palladium(II) dichloride

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 77462-40-9
PdI₂(bis(diphenylphosphino)methane)

Guidance literature:: In methanol; dichloromethane; water; N2-atmosphere; addn. of excess NaI (in aq. MeOH) to Pd-complex (in CH2Cl2), stirring for 1 h; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (aq. MeOH, Et2O), drying (vac.); elem. anal.;

Reference yield: 24.0%

: 67477-87-6
Pd2I2(μ-bis(diphenylphosphino)methane)2

: 7783-55-3
trifluorophosphane

: 77462-40-9
PdI₂(bis(diphenylphosphino)methane)

: {Pd(μ3-trifluorophosphine)(μ3-I)(μ-bis(diphenylphosphino)methane)3}I

Guidance literature:: In dichloromethane; stirred for 67 h under 1 atm of PF3; filtered, concd., addn. of diethyl ether, ppt. filtered, washed with CHCl3 (residue: Pd(dpm)Cl2), column chromy. (alumina, CHCl3), addn. of KPF6 in MeOH, evapd. to dryness, 3 times recrystd. (CH2Cl2/diethyl ether);

Reference yield:

: 64345-29-5
Pd2Cl2(μ-bis(diphenylphosphino)methane)2

: 624-74-8
diiodoacetylene

: {Pd2ClI(μ-σ-CCCl2)(μ-Ph2PCH2PPh2)2}

: {Pd2I2(μ-σ-CCCl2)(μ-Ph2PCH2PPh2)2}

: {Pd2Cl2(μ-σ-CCCl2)(μ-Ph2PCH2PPh2)2}

: 77462-40-9
PdI₂(bis(diphenylphosphino)methane)

Guidance literature:: In benzene; Pd compound refluxed with 1 equiv of ICCI in benzene; solvent removed in vac.; components of the product sepd. by extn. with THF and crystn. from CHCl3-heptane;
DOI:10.1039/c39880000047