Iodomethyl methyl sulfide

Base Information

• Chemical Name: Iodomethyl methyl sulfide
• CAS No.: 43034-68-0
• Molecular Formula: C2H5IS
• Molecular Weight: 188.032
• DSSTox Substance ID: DTXSID40195646
• Nikkaji Number: J1.354.601K
• Wikidata: Q83068661
• Mol file: 43034-68-0.mol

Synonyms:Iodomethyl methyl sulfide;43034-68-0;iodo(methylsulfanyl)methane;methyl iodomethyl sulfide;SCHEMBL9695926;DTXSID40195646

Chemical Property of Iodomethyl methyl sulfide

Chemical Property:

• Vapor Pressure: 4.04mmHg at 25°C
• Boiling Point: 154.7°C at 760 mmHg
• Flash Point: 47.3°C
• Density: 1.993g/cm³
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 187.91567
• Heavy Atom Count: 4
• Complexity: 10

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CSCI

Technology Process of Iodomethyl methyl sulfide

There total 4 articles about Iodomethyl methyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

trans-chloro(thiomethoxymethyl)bis(triphenylphosphine)platinum(II)*CH2Cl2 → diiodobis(triphenylphosphine)platinum(II) (23523-31-1,35085-01-9,35085-00-8) + chloro-methylsulfanyl-methane (2373-51-5) + iodo(methylsulfanyl)methane (43034-68-0) + (P(C6H5)3)2PtICl

Guidance literature:

In chloroform-d1; byproducts: I2; addn. of halogen to soln. of complex; amts. of products detected by (1)H-NMR;

DOI:10.1016/S0022-328X(00)99112-5

Reference yield: 14.0%

acetyl iodide (507-02-8) + dimethyl sulfoxide (67-68-5,8070-53-9) → dimethylsulfide (75-18-3) + iodo(methylsulfanyl)methane (43034-68-0) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

at 20 - 80 ℃; Mechanism;

DOI:10.1134/S1070428014100236

Reference yield:

chloromethyl dimethylsulfonium tetrafluoroborate → iodo(methylsulfanyl)methane (43034-68-0) + methyl iodide (74-88-4)

Guidance literature:

With benzyltrimethylammonium iodide; In [D₃]acetonitrile; at 25 ℃; Further Variations:; Temperatures; Reagents; Kinetics; Thermodynamic data; Activation energy;

DOI:10.1021/jo000015f

upstream raw materials:

dimethylsulfide

acetyl iodide

dimethyl sulfoxide

Downstream raw materials:

p-nitrobenzyl (4R,5S,6S)-6-[1'(R)-hydroxyethyl]-4-methyl-3-[[(methylthio)methyl]thio]-7-oxo-1-azabicyclo[3.2.0]-hept-2-ene-2-carboxylate

(R)-4-methyl-4-methylsulfanylmethyl-5-oxo-2-phenyloxazolidine-3-carboxylic acid benzyl ester