methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

Base Information

Chemical Name:methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate
CAS No.:1096143-66-6
Molecular Formula:C₄₉H₅₆O₁₀Si
Molecular Weight:833.063
Hs Code.:

Synonyms:methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

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Chemical Property of methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

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Technology Process of methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

There total 2 articles about methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α/β-D-glucopyranoside

: 142564-20-3
(-)-methyl-(2R)-3-(tert-butyldiphenylsilyloxy)-2-hyrdoxypropanoate

: 1096143-66-6
methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; 1-benzenesulfinyl piperidine; trifluoromethylsulfonic anhydride; In dichloromethane; at -78 - 0 ℃; for 0.416667h; Molecular sieve;
DOI:10.1016/j.carres.2008.08.030

Reference yield:

: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α/β-D-glucopyranoside

: 142564-20-3
(-)-methyl-(2R)-3-(tert-butyldiphenylsilyloxy)-2-hyrdoxypropanoate

: 1096143-66-6
methyl 3-O-tert-butyldiphenylsilyl-(2R)-2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-2,3-dihydroxypropanoate

: C₄₉H₅₆O₁₀Si

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; at 0 ℃; for 0.5h; optical yield given as %de; Inert atmosphere; Molecular sieve;
DOI:10.1016/j.carres.2009.06.037