1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

Base Information

Chemical Name:1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol
CAS No.:101713-62-6
Molecular Formula:C₁₇H₂₇NO₇Si
Molecular Weight:385.489
Hs Code.:

Synonyms:1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

Chemical Property:

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Technology Process of 1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

There total 3 articles about 1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 101713-61-5
1-O-<((2-nitrobenzyl)oxy)carbonyl>glycerol

: 101713-62-6
1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

Guidance literature:: With silver nitrate; In tetrahydrofuran; at 25 ℃; for 30h;
DOI:10.1021/jo00360a001

Reference yield:

: 42854-99-9
o-nitrobenzyl chloroformate

: 101713-62-6
1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h

2: 80 percent / 1percent aq. H₂SO₄ / acetone / 31 h / 25 °C

3: 78 percent / AgNO₃ / tetrahydrofuran / 30 h / 25 °C

With dmap; sulfuric acid; silver nitrate; In tetrahydrofuran; dichloromethane; acetone;
DOI:10.1021/jo00360a001

Reference yield:

: 101713-60-4
1-O-<((2-nitrobenzyl)oxy)carbonyl>-2,3-O-isopropylideneglycerol

: 101713-62-6
1-O-<((2-nitrobenzyl)oxy)carbonyl>-3-O-(tert-butyldimethylsilyl)glycerol

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / 1percent aq. H₂SO₄ / acetone / 31 h / 25 °C

2: 78 percent / AgNO₃ / tetrahydrofuran / 30 h / 25 °C

With sulfuric acid; silver nitrate; In tetrahydrofuran; acetone;
DOI:10.1021/jo00360a001