Bis(4-chloro-3-nitrophenyl) sulphone

Base Information

• Chemical Name: Bis(4-chloro-3-nitrophenyl) sulphone
• CAS No.: 1759-05-3
• Molecular Formula: C12H6 Cl2 N2 O6 S
• Molecular Weight: 377.161
• Hs Code.: 2904909090
• European Community (EC) Number: 217-159-9
• NSC Number: 4447
• DSSTox Substance ID: DTXSID50170040
• Nikkaji Number: J64.478A
• Wikidata: Q72444684
• Mol file: 1759-05-3.mol

Synonyms:1759-05-3;Bis(4-chloro-3-nitrophenyl) sulphone;bis(4-chloro-3-nitrophenyl) sulfone;1-chloro-4-(4-chloro-3-nitrophenyl)sulfonyl-2-nitrobenzene;NSC4447;Sulfone, bis(4-chloro-3-nitrophenyl);Benzene,1,1'-sulfonylbis[4-chloro-3-nitro-;Benzene, 1,1'-sulfonylbis[4-chloro-3-nitro-;NSC 4447;EINECS 217-159-9;1-chloro-4-(4-chloro-3-nitrobenzenesulfonyl)-2-nitrobenzene;AI3-04010;1,1'-sulfonylbis(4-chloro-3-nitrobenzene);Benzene, 1,1'-sulfonylbis(4-chloro-3-nitro-;1-chloro-4-[(4-chloro-3-nitrophenyl)sulphonyl]-2-nitrobenzene;1,1'-Sulfonylbis[4-chloro-3-nitrobenzene];Bis(4-chloro-3-nitrophenyl)sulphone;SCHEMBL809482;DTXSID50170040;1-chloro-4-(4-chloro-3-nitro-phenyl)sulfonyl-2-nitro-benzene;BAA75905;NSC-4447;MFCD00044066;STK332538;AKOS001038416;4-CHLORO-3-NITROPHENYL SULFONE;Benzene,1'-sulfonylbis[4-chloro-3-nitro-;Diphenylsulfone,4'-dichloro-3,3'-dinitro-;4,4'-Dichloro-3,3'-dinitrodiphenyl sulfone;4,4'-Sulfonylbis(1-chloro-2-nitrobenzene);CS-0268940;FT-0739729;3,3'-Dinitro-4, 4'-dichlorodiphenyl sulfone;Diphenylsulfone, 4,4'-dichloro-3,3'-dinitro-;Benzene, {1,1'-sulfonylbis[4-chloro-3-nitro-};Z56757028;(2-Chloro-5-((4-chloro-3-(hydroxy(oxido)amino)phenyl)sulfonyl)phenyl)(hydroxy)azane oxide

Chemical Property of Bis(4-chloro-3-nitrophenyl) sulphone

Chemical Property:

• Vapor Pressure: 4.89E-12mmHg at 25°C
• Boiling Point: 561°Cat760mmHg
• Flash Point: 293.1°C
• PSA: 134.16000
• Density: 1.673g/cm³
• LogP: 5.76980
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 2
• Exact Mass: 375.9323625
• Heavy Atom Count: 23
• Complexity: 526

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-CHLORO-3-NITROPHENYL SULFONE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C=C1S(=O)(=O)C2=CC(=C(C=C2)Cl)[N+](=O)[O-])[N+](=O)[O-])Cl

Technology Process of Bis(4-chloro-3-nitrophenyl) sulphone

There total 5 articles about Bis(4-chloro-3-nitrophenyl) sulphone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4,4'-dichlorodiphenyl sulphone (80-07-9,30605-10-8,85228-26-8,36313-66-3) → bis(4-chloro-3-nitrophenyl)sulfone (1759-05-3)

Guidance literature:

With sulfuric acid; nitric acid; In 1,2-dichloro-ethane;

Reference yield:

chlorobenzene (108-90-7) → bis(4-chloro-3-nitrophenyl)sulfone (1759-05-3)

Guidance literature:

Multi-step reaction with 3 steps

1: fuming sulfuric acid; hydrogen chloride / Edukt 4:SO₃

2: AlCl₃

3: H₂SO₄; HNO₃

With hydrogenchloride; aluminium trichloride; sulfuric acid; nitric acid;

Reference yield:

4-chlorobenzenesulfonyl chloride (98-60-2) → bis(4-chloro-3-nitrophenyl)sulfone (1759-05-3)

Guidance literature:

Multi-step reaction with 2 steps

1: AlCl₃

2: H₂SO₄; HNO₃

With aluminium trichloride; sulfuric acid; nitric acid;

upstream raw materials:

4,4'-dichlorodiphenyl sulphone

4-chlorobenzenesulfonyl chloride

chlorobenzene

Downstream raw materials:

bis-[4-(2-diethylamino-ethylamino)-3-nitro-phenyl]-sulfone

N,N'-[4,4'-sulfinylbis(2-nitro-4,1-phenylene)]diacetamide

C₂₄H₁₈N₄O₈S

Bis-<3-nitro-4-p-tolyloxy-phenyl>-sulfon

Refernces

• 1、 Borjigin, Hailun,Stevens, Kevin A.,Liu, Ran,Moon, Joshua D.,Shaver, Andrew T.,Swinnea, Steve,Freeman, Benny D.,Riffle,McGrath, James E.. "Synthesis and characterization of polybenzimidazoles derived from tetraaminodiphenylsulfone for high temperature gas separation membranes". . p. 135 - 142. Retrieved 2015/07/28.
• 2、 Dutta, Pradip K.,Maiti, Sukumar. "Synthesis and curing of bissulphone". . p. 1023 - 1028. Retrieved 2007/10/02.