(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

Base Information

Chemical Name:(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol
CAS No.:604774-88-1
Molecular Formula:C₂₀H₂₇BO₂
Molecular Weight:310.244
Hs Code.:

Synonyms:(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

Chemical Property:

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Technology Process of (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

There total 1 articles about (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 31503-17-0
(-)-(1R,2R,3R,4S)-1,7,7-trimethyl-2-phenyl-bicyclo[2.2.1]heptane-2,3-diol

: 99687-39-5
(E)-but-2-en-1-ylboronic acid

: 604774-88-1
(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

Guidance literature:: In diethyl ether; at 20 ℃; for 0.75h;
DOI:10.1021/ja036807j

Reference yield: 71.0%

: 104-53-0
3-phenyl-propionaldehyde

: 604774-88-1
(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

: 207503-57-9
(-)-(3S,4R)-4-methyl-1-phenylhex-5-en-3-ol

Guidance literature:: 3-phenyl-propionaldehyde; (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol; With scandium tris(trifluoromethanesulfonate); In dichloromethane; at -78 ℃; for 24h;

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1h;
DOI:10.1021/ja036807j

Reference yield: 60.0%

: 100-52-7
benzaldehyde

: 604774-88-1
(1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol

: 25201-44-9,52922-10-8,52922-19-7,63553-62-8,63553-63-9,103882-39-9,103882-41-3,122332-13-2,121842-16-8
(1R,2R)-2-methyl-1-phenylbut-3-en-1-ol

Guidance literature:: benzaldehyde; (1R,2S,3R,4S)-2,3-O-[(E)-2-butenylboryl]-2-phenyl-1,7,7-trimethylbornanediol; With scandium tris(trifluoromethanesulfonate); In dichloromethane; at -78 ℃; for 24h;

With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 1h;
DOI:10.1021/ja036807j