phenyl-2,4,6-trimethoxyphenylselenide

Base Information

• Chemical Name: phenyl-2,4,6-trimethoxyphenylselenide
• CAS No.: 120571-20-2
• Molecular Formula: C₁₅H₁₆O₃Se
• Molecular Weight: 323.25
• Mol file: 120571-20-2.mol

Synonyms:phenyl-2,4,6-trimethoxyphenylselenide

Chemical Property of phenyl-2,4,6-trimethoxyphenylselenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenyl-2,4,6-trimethoxyphenylselenide

There total 11 articles about phenyl-2,4,6-trimethoxyphenylselenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,2,3-trimethoxybenzene (621-23-8) + diphenyl diselenide (1666-13-3) → phenyl-2,4,6-trimethoxyphenylselenide (120571-20-2)

Guidance literature:

With iridium(III) bis[2-(4,6-difluorophenyl)pyridinato]picolinate; In acetonitrile; at 25 ℃; Irradiation; Green chemistry;

DOI:10.1039/c7gc02803b

Reference yield: 87.0%

1,2,3-trimethoxybenzene (621-23-8) + phenyl selenocyanate (2179-79-5) → phenyl-2,4,6-trimethoxyphenylselenide (120571-20-2)

Guidance literature:

With 1,1,1,3',3',3'-hexafluoro-propanol; In 1,2-dichloro-ethane; at 20 ℃; for 10h; Solvent; Temperature; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.joc.1c00478

Reference yield: 65.0%

1,2,3-trimethoxybenzene (621-23-8) + N-phenylselanylphthalimide (71098-88-9) + cis-1-phenyl-1-propylene (766-90-5) → phenyl-2,4,6-trimethoxyphenylselenide (120571-20-2) + 2,4,6-trimethoxy-1-[1-phenyl-2-(phenylseleno)propyl]benzene

Guidance literature:

N-phenylselanylphthalimide; With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 ℃; for 0.5h; Inert atmosphere;

cis-1-phenyl-1-propylene; In dichloromethane; at -78 ℃; for 0.5h; Inert atmosphere;

1,2,3-trimethoxybenzene; In dichloromethane; at -78 - -20 ℃; for 9h; regioselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.5b03579

upstream raw materials:

1,2,3-trimethoxybenzene

diphenyl diselenide

N-phenylselanylphthalimide

cis-1-phenyl-1-propylene