(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

Base Information

Chemical Name:(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene
CAS No.:91445-12-4
Molecular Formula:C₁₅H₂₄O
Molecular Weight:220.355
Hs Code.:

Synonyms:(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

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Technology Process of (Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

There total 2 articles about (Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 91445-08-8
(Z)-1-<<1-(Trimethylsilyl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

: 67-64-1
acetone

: 91445-12-4
(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 10h; Heating;
DOI:10.1021/jo00193a031

Reference yield:

: 40790-56-5
2,6-dimethyl-2-cyclohexen-1-one

: 91445-12-4
(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / Anhydrous TiCl₃, Zn/Cu / 1,2-dimethoxy-ethane / 1) 3 h, room temperature, 2) reflux, 30 h

2: 90 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 10 h / Heating

With titanium(III) chloride; tetrabutyl ammonium fluoride; copper; zinc; In tetrahydrofuran; 1,2-dimethoxyethane;
DOI:10.1021/jo00193a031

Reference yield:

: 91445-12-4
(Z)-1-<<1-(2-Hydroxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

: 74-88-4
methyl iodide

: 91445-13-5
(Z)-1-<<1-(2-Methoxyprop-2-yl)cyclopropyl>methylene>-2,6-dimethyl-2-cyclohexene

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; Yield given. Multistep reaction; 1) THF, 0 deg C, 10 min, 2) 25 deg C, 20 h;
DOI:10.1021/jo00193a031