(S)-o-bromobenzhydrol

Base Information

Chemical Name:(S)-o-bromobenzhydrol
CAS No.:143880-86-8
Molecular Formula:C₁₃H₁₁BrO
Molecular Weight:263.134
Hs Code.:

Synonyms:(S)-o-bromobenzhydrol

Suppliers and Price of (S)-o-bromobenzhydrol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of (S)-o-bromobenzhydrol

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-o-bromobenzhydrol

There total 20 articles about (S)-o-bromobenzhydrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.4%

: 13047-06-8
o-bromobenzophenone

: 143880-86-8
(S)-o-bromobenzhydrol

Guidance literature:: With trans-RuCl₂[(S)-xylbinap][(S)-daipen]; potassium tert-butylate; hydrogen; In isopropyl alcohol; tert-butyl alcohol; at 23 ℃; for 13h; under 6080.41 Torr;
DOI:10.1021/ol9904139

Reference yield: 98.0%

: 100-52-7
benzaldehyde

: 244205-40-1
(2-bromophenyl)boronic acid

: 143880-86-8
(S)-o-bromobenzhydrol

Guidance literature:: (2-bromophenyl)boronic acid; With diethylzinc; In toluene; at 60 ℃; for 0.25h; Inert atmosphere;

With C₄₆H₃₈NOP; In toluene; at 20 ℃; for 0.25h; Inert atmosphere;

benzaldehyde; optical yield given as %ee; enantioselective reaction; Further stages;
DOI:10.1016/j.tet.2009.12.009

Reference yield: 92.0%

: 3262-89-3
triphenylboroxine

: 6630-33-7
ortho-bromobenzaldehyde

: 143880-86-8
(S)-o-bromobenzhydrol

Guidance literature:: triphenylboroxine; With diethylzinc; In toluene; at 60 ℃; for 4h;

ortho-bromobenzaldehyde; With (S)-dendritic pyrrolidinylmethanol C₁₁₆H₁₀₅NO₁₅; In toluene; at -15 ℃; for 6h;
DOI:10.1021/jo050994h