2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆

Base Information

• Chemical Name: 2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆
• CAS No.: 85335-13-3
• Molecular Formula: 2C₂₁H₂₀P*I₆Re
• Molecular Weight: 1554.36
• Mol file: 85335-13-3.mol

Synonyms:2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆

Chemical Property of 2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆

There total 2 articles about 2(C₆H₅)3PC₃H₅⁽¹⁺⁾*ReI₆^(2-)=((C₆H₅)3PC₃H₅)2ReI₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

allyl iodid (556-56-9) + ReH7*2P(C6H5)3=ReH7(P(C6H5)3)2 (12103-40-1) → propane (74-98-6) + 2(C6H5)3PC3H5(1+)*ReI6(2-)=((C6H5)3PC3H5)2ReI6 (85335-13-3)

Guidance literature:

In tetrahydrofuran; byproducts: H2, propene; under N2, allyl iodide was reacted with Re-complex with stirring in THFat room temp. for 3 h; filtered, washed with THF and Et2O, recrystd. from CH2Cl2-THF; elem. anal.;

Reference yield: 66.0%

Re2(μ-H)4H4(triphenylphosphine)4 + allyl iodid (556-56-9) → 2(C6H5)3PC3H5(1+)*ReI6(2-)=((C6H5)3PC3H5)2ReI6 (85335-13-3)

Guidance literature:

In tetrahydrofuran; byproducts: H2, propene; under N2, mixt. of allyl iodide and Re-complex in THF was stirred at room temp. for 3 h; filtered, washed with THF, recrystd. from CH2Cl2-THF; elem. anal.;

upstream raw materials:

allyl iodid

ReH₇*2P(C₆H₅)3=ReH₇(P(C₆H₅)3)2

Refernces