(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

Base Information

Chemical Name:(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol
CAS No.:882175-55-5
Molecular Formula:C₁₅H₂₈O₃Si
Molecular Weight:284.471
Hs Code.:

Synonyms:(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

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Chemical Property of (E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

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Technology Process of (E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

There total 8 articles about (E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 882175-71-5
(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-acrylic acid methyl ester

: 882175-55-5
(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In toluene;
DOI:10.3987/com-05-s(t)70

Reference yield:

: 3413-44-3
(R)-2-cyclohexen-1-ol

: 882175-55-5
(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 84 percent / imidazole / CH₂Cl₂

2: m-chloroperbenzoic acid; NaHCO₃ / CH₂Cl₂ / 0 °C

3: [C(CH₃)2(CH₂)3C(CH₃)2]NLi / hexane; benzene / 0 - 20 °C

4: 87 percent / tri-n-butylphosphine / CH₂Cl₂ / 0.08 h / 22 °C

5: 86 percent / DIBAL / toluene

With 1H-imidazole; tributylphosphine; 2,2,6,6-tetramethylpiperidinyl-lithium; diisobutylaluminium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In hexane; dichloromethane; toluene; benzene;
DOI:10.3987/com-05-s(t)70

Reference yield:

: 882175-52-2
tert-butyl-(cyclohex-2-enyloxy)-dimethyl-silane

: 882175-55-5
(E)-3-[(1R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-cyclohex-2-enyloxy]-prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 4 steps

1: m-chloroperbenzoic acid; NaHCO₃ / CH₂Cl₂ / 0 °C

2: [C(CH₃)2(CH₂)3C(CH₃)2]NLi / hexane; benzene / 0 - 20 °C

3: 87 percent / tri-n-butylphosphine / CH₂Cl₂ / 0.08 h / 22 °C

4: 86 percent / DIBAL / toluene

With tributylphosphine; 2,2,6,6-tetramethylpiperidinyl-lithium; diisobutylaluminium hydride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In hexane; dichloromethane; toluene; benzene;
DOI:10.3987/com-05-s(t)70