4-Methylbenzaldehyde oxime

Base Information

Chemical Name:4-Methylbenzaldehyde oxime
CAS No.:3235-02-7
Molecular Formula:C₈H₉NO
Molecular Weight:135.166
Hs Code.:
European Community (EC) Number:659-488-4
NSC Number:45454
UNII:RMF45F3N6C
Nikkaji Number:J119.250G
Wikidata:Q82861543
Mol file:3235-02-7.mol

Synonyms:4-Methylbenzaldehyde oxime;3235-02-7;3717-15-5;N-[(4-methylphenyl)methylidene]hydroxylamine;4-Methylbenzaldoxime;p-Tolualdehyde, oxime;Benzaldehyde, 4-methyl-, oxime;(NE)-N-[(4-methylphenyl)methylidene]hydroxylamine;(E)-4-Methylbenzaldehyde oxime;p-Tolualdoxime;NSC-45454;(alphaE)-N-Hydroxy-4-methylbenzenemethaneimine;p-methylbenzaldehyde oxime;4-Methylbenzaldehyde oxime #;p-Tolualdehyde, oxime, (Z)-;(Z)-4-Methylbenzaldehyde oxime;Benzaldehyde, 4-methyl-, oxime, (Z)-;p-Tolualdehyde oxime;E-4-Methylbenzaldoxime;4-methyl-benzaldehyde-oxime;4-TOLUALDEHYDE OXIME;RMF45F3N6C;SCHEMBL762978;4-Methylbenzaldehyde (E)-oxime;trans-4-Methylbenzaldehyde oxime;SRNDYVBEUZSFEZ-RMKNXTFCSA-N;HMS1783C20;4-Methylbenzaldehyde oxime, (E)-;NSC45454;NSC 45454;AKOS001050878;NCGC00323076-01;3717-16-6;Benzaldehyde, 4-methyl-, oxime, [C(E)]-;CS-0179148;CS-0356298;EN300-07985;AB01318559-02;A936801;Z49568558;(Z)-N-[(4-METHYLPHENYL)METHYLIDENE]HYDROXYLAMINE

Suppliers and Price of 4-Methylbenzaldehyde oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
(E)-4-Methylbenzaldehydeoxime 95+%
5g
$ 570.00

American Custom Chemicals Corporation
4-METHYLBENZALDEHYDE OXIME 95.00%
5G
$ 1421.65

American Custom Chemicals Corporation
4-METHYLBENZALDEHYDE OXIME 95.00%
2.5G
$ 1147.43

American Custom Chemicals Corporation
4-METHYLBENZALDEHYDE OXIME 95.00%
1G
$ 808.89

AK Scientific
4-Methylbenzaldehydeoxime
1g
$ 504.00

Total 12 raw suppliers

Chemical Property of 4-Methylbenzaldehyde oxime

Chemical Property:

Melting Point:76-78 °C
Boiling Point:216.8°Cat760mmHg
PKA:10.83±0.10(Predicted)
Flash Point:116.4°C
PSA：32.59000
Density:1.01g/cm³
LogP:1.80310
XLogP3:2.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:135.068413911
Heavy Atom Count:10
Complexity:114

Purity/Quality:

97% ^*data from raw suppliers

(E)-4-Methylbenzaldehydeoxime 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C=NO
Isomeric SMILES:CC1=CC=C(C=C1)/C=N/O

Technology Process of 4-Methylbenzaldehyde oxime

There total 20 articles about 4-Methylbenzaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 104-87-0
4-methyl-benzaldehyde

: 3235-02-7,3717-15-5,3717-16-6,140461-26-3,140461-27-4
p-methylbenzaldehyde oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium carbonate; In ethanol; at 20 ℃;
DOI:10.1039/c2ob26699g

Reference yield: 93.0%

: 589-18-4
4-Methylbenzyl alcohol

: 3235-02-7,3717-15-5,3717-16-6,140461-26-3,140461-27-4
p-methylbenzaldehyde oxime

Guidance literature:: 4-Methylbenzyl alcohol; With dihydrogen peroxide; at 20 ℃; for 0.166667h; Green chemistry;

With hydroxylamine hydrochloride; for 4h; Catalytic behavior; Green chemistry;
DOI:10.1016/j.molstruc.2019.03.008

Reference yield: 90.0%

: 106-38-7
para-bromotoluene

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 3235-02-7,3717-15-5,3717-16-6,140461-26-3,140461-27-4
p-methylbenzaldehyde oxime

Guidance literature:: para-bromotoluene; With n-butyllithium; In tetrahydrofuran; hexane; at -50 ℃; for 0.5h; Inert atmosphere;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -50 - 20 ℃; for 1h; Inert atmosphere;

With hydroxylamine hydrochloride; potassium carbonate; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Reagent/catalyst; Temperature; Inert atmosphere;
DOI:10.1016/j.tet.2018.06.044