(S)-tert-butyl 2-(2'-anisyl)propionate

Base Information

Chemical Name:(S)-tert-butyl 2-(2'-anisyl)propionate
CAS No.:1334591-55-7
Molecular Formula:C₁₄H₂₀O₃
Molecular Weight:236.311
Hs Code.:

Synonyms:(S)-tert-butyl 2-(2'-anisyl)propionate

Suppliers and Price of (S)-tert-butyl 2-(2'-anisyl)propionate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-tert-butyl 2-(2'-anisyl)propionate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-tert-butyl 2-(2'-anisyl)propionate

There total 4 articles about (S)-tert-butyl 2-(2'-anisyl)propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 72658-10-7
tert-butyl trimethylsilyl methyl ketene acetal

: 59099-58-0
o-anisyl trifluoromethanesulfonate

: 1334591-55-7
(S)-tert-butyl 2-(2'-anisyl)propionate

Guidance literature:: With zinc(II) fluoride; (R)-2-(dicyclohexylphosphino)-2'-(2-naphthylmethoxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; lithium acetate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In α,α,α-trifluorotoluene; at 50 ℃; for 36h; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ja2066829

Reference yield: 91.0%

: 1334591-55-7
(S)-tert-butyl 2-(2'-anisyl)propionate

Guidance literature:: With (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II); (R)-2-(dicyclohexylphosphino)-2'-(2-naphthylmethoxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; lithium acetate; at 50 ℃; for 18h; Inert atmosphere;

Reference yield:

: 20487-40-5
tert-butyl propionate

: 1334591-55-7
(S)-tert-butyl 2-(2'-anisyl)propionate

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium; diisopropylamine / cyclohexane; cyclopentyl methyl ether / 0.83 h / 0 °C / Inert atmosphere

1.2: 2.25 h / 0 °C / Inert atmosphere

2.1: zinc(II) fluoride; (R)-2-(dicyclohexylphosphino)-2'-(2-naphthylmethoxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; lithium acetate; bis(dibenzylideneacetone)-palladium(0) / α,α,α-trifluorotoluene / 36 h / 50 °C / Inert atmosphere

With n-butyllithium; zinc(II) fluoride; (R)-2-(dicyclohexylphosphino)-2'-(2-naphthylmethoxy)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; lithium acetate; diisopropylamine; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In cyclohexane; α,α,α-trifluorotoluene; cyclopentyl methyl ether;
DOI:10.1021/ja2066829